Fabrication of superhydrophobic Enteromorpha-derived carbon aerogels via NHHPO modification for multi-behavioral oil/water separation.

Hydrophobic and oleophilic biomass-based block materials are considered to be highly promising candidates used for oil/water separation. However, the crucial hydrophobic modification process often involves various toxic and hazardous organic substances or requires high energy inputs. Inspired by the flame retardant principle of phosphorus-containing flame retardants, herein, an Enteromorpha-derived carbon (ADP-EP) aerogel with a water contact angle of 144.2° was prepared by successive freeze-shaping, freeze-drying and low-temperature carbonization treatment (300 °C), using NHHPO (ADP) as a modifier. The results demonstrated that the introduction of NHHPO could largely facilitate the removal of oxygenated groups from the pristine EP aerogels and enhance their surface roughness, thereby achieving surface hydrophobic modification. Featuring intrinsic low density, rich porosity and strong lipophilicity, the as-fabricated ADP-EP aerogels exhibited exceptional performance in both oil spill adsorption (~140 g/g) and water-in-oil emulsion separation. Moreover, the good reusability for oil uptake was also realized thanks to its robust mechanical compressibility and thermal stability. This work provides a facile, economical and eco-friendly route to obtain a desirable hydrophobic/oleophilic surface.