Photoelectrochemical Response Enhancement for Metallofullerene-[12]Cycloparaphenylene Supramolecular Complexes.

The photoelectrochemical properties of three metallofullerene-[12]cycloparaphenylene ([12]CPP) supramolecular complexes of ScN@C⊂[12]CPP, ScN@C⊂[12]CPP, and ScC@C⊂[12]CPP were studied. It was revealed that the photocurrent responses of these supramolecular complexes show enhancement compared with those of pristine metallofullerenes, indicating the efficient photocurrent generation and promoted charge carrier transport caused by the supramolecular interaction. The results show that ScC@C and ScC@C⊂[12]CPP have the strongest photocurrents. Then, by comparing the photocurrent intensities of the metallofullerene-biphenyl derivates mixture and the metallofullerene⊂[12]CPP complexes, it was demonstrated that the host-guest interaction is the key factor promoting photocurrent enhancement. At the same time, by observing the microscopic morphologies of pristine fullerenes and supramolecular complexes, it was found that the construction of supramolecules helps to improve the morphology of metallofullerenes on FTO glass. Additionally, their electrical conductivity in optoelectronic devices was tested, respectively, indicating that the construction of supramolecules facilitates the transport of charge carriers. This work discloses the potential application of metallofullerene supramolecular complexes as photodetector and photoelectronic materials.