非血红素过氧二铁(III)、酰基过氧和碘代苯铁(III)中间体介导的催化和计量氧化。
Catalytic and Stoichiometric Oxidation Mediated by Nonheme Peroxo-Diiron(III), Acylperoxo, and Iodosylbenzene Iron(III) Intermediates.
机构信息
Research Group of Bioorganic and Biocoordination Chemistry, Faculty of Engineering, Center for Natural Sciences, University of Pannonia, H-8201 Veszprém, Hungary.
出版信息
Molecules. 2022 Apr 28;27(9):2814. doi: 10.3390/molecules27092814.
In this paper we describe a detailed mechanistic studies on the [Fe(PBO)(CFSO)] (), [Fe(PBT)(CFSO)] (), and Fe(PBI) ()-catalyzed (PBO = 2-(2'-pyridyl)benzoxazole, PBT = 2-(2'-pyridyl)benzthiazole, PBI = 2-(2'-pyridyl)benzimidazole) oxidation of cycloketones by dioxygen with cooxidation of aldehydes and peroxycarboxylic acids, including the kinetics on the reactivity of (μ-1,2-peroxo)diiron(III), acylperoxo- and iodosylbenzene-iron(III) species as key intermediates.
在本文中，我们详细描述了 [Fe(PBO)(CFSO)] (), [Fe(PBT)(CFSO)] (), 和 Fe(PBI) ()-催化的（PBO = 2-(2'-吡啶基)苯并恶唑，PBT = 2-(2'-吡啶基)苯并噻唑，PBI = 2-(2'-吡啶基)苯并咪唑）环酮与醛和过氧羧酸的共氧化的双氧合氧（dioxygen）氧化反应的详细机理研究，包括（μ-1,2-过氧）二铁(III)、酰基过氧和碘代苯并铁(III)物种作为关键中间体的反应动力学。
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