• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

非血红素过氧二铁(III)、酰基过氧和碘代苯铁(III)中间体介导的催化和计量氧化。

Catalytic and Stoichiometric Oxidation Mediated by Nonheme Peroxo-Diiron(III), Acylperoxo, and Iodosylbenzene Iron(III) Intermediates.

机构信息

Research Group of Bioorganic and Biocoordination Chemistry, Faculty of Engineering, Center for Natural Sciences, University of Pannonia, H-8201 Veszprém, Hungary.

出版信息

Molecules. 2022 Apr 28;27(9):2814. doi: 10.3390/molecules27092814.

DOI:10.3390/molecules27092814
PMID:35566165
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9100052/
Abstract

In this paper we describe a detailed mechanistic studies on the [Fe(PBO)(CFSO)] (), [Fe(PBT)(CFSO)] (), and Fe(PBI) ()-catalyzed (PBO = 2-(2'-pyridyl)benzoxazole, PBT = 2-(2'-pyridyl)benzthiazole, PBI = 2-(2'-pyridyl)benzimidazole) oxidation of cycloketones by dioxygen with cooxidation of aldehydes and peroxycarboxylic acids, including the kinetics on the reactivity of (μ-1,2-peroxo)diiron(III), acylperoxo- and iodosylbenzene-iron(III) species as key intermediates.

摘要

在本文中，我们详细描述了 [Fe(PBO)(CFSO)] (), [Fe(PBT)(CFSO)] (), 和 Fe(PBI) ()-催化的（PBO = 2-(2'-吡啶基)苯并恶唑，PBT = 2-(2'-吡啶基)苯并噻唑，PBI = 2-(2'-吡啶基)苯并咪唑）环酮与醛和过氧羧酸的共氧化的双氧合氧（dioxygen）氧化反应的详细机理研究，包括（μ-1,2-过氧）二铁(III)、酰基过氧和碘代苯并铁(III)物种作为关键中间体的反应动力学。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/4e854deea04e/molecules-27-02814-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/c2a3b0528da8/molecules-27-02814-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/1a22a551899b/molecules-27-02814-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/c97945a43318/molecules-27-02814-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/7c17ee988f8a/molecules-27-02814-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/4927c814926f/molecules-27-02814-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/26809873df7c/molecules-27-02814-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/4c194751d662/molecules-27-02814-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/4f4dfdc33553/molecules-27-02814-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/f2d161f19339/molecules-27-02814-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/a95580e6949f/molecules-27-02814-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/8026fbd3f11a/molecules-27-02814-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/1d7c0bc4c25d/molecules-27-02814-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/bb59e25eb0ca/molecules-27-02814-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/4e854deea04e/molecules-27-02814-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/c2a3b0528da8/molecules-27-02814-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/1a22a551899b/molecules-27-02814-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/c97945a43318/molecules-27-02814-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/7c17ee988f8a/molecules-27-02814-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/4927c814926f/molecules-27-02814-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/26809873df7c/molecules-27-02814-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/4c194751d662/molecules-27-02814-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/4f4dfdc33553/molecules-27-02814-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/f2d161f19339/molecules-27-02814-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/a95580e6949f/molecules-27-02814-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/8026fbd3f11a/molecules-27-02814-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/1d7c0bc4c25d/molecules-27-02814-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/bb59e25eb0ca/molecules-27-02814-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84f3/9100052/4e854deea04e/molecules-27-02814-sch002.jpg

相似文献

1
Catalytic and Stoichiometric Oxidation Mediated by Nonheme Peroxo-Diiron(III), Acylperoxo, and Iodosylbenzene Iron(III) Intermediates.非血红素过氧二铁(III)、酰基过氧和碘代苯铁(III)中间体介导的催化和计量氧化。
Molecules. 2022 Apr 28;27(9):2814. doi: 10.3390/molecules27092814.
2
Synthetic mononuclear nonheme iron-oxygen intermediates.合成单核非血红素铁-氧中间体。
Acc Chem Res. 2015 Aug 18;48(8):2415-23. doi: 10.1021/acs.accounts.5b00218. Epub 2015 Jul 23.
3
Dioxygen activation and catalytic aerobic oxidation by a mononuclear nonheme iron(II) complex.单核非血红素铁（II）配合物对双氧的活化及催化需氧氧化反应
J Am Chem Soc. 2005 Mar 30;127(12):4178-9. doi: 10.1021/ja043083i.
4
Effect of Redox Potential on Diiron-Mediated Disproportionation of Hydrogen Peroxide.氧化还原电势对二铁介导的过氧化氢歧化反应的影响。
Molecules. 2023 Mar 23;28(7):2905. doi: 10.3390/molecules28072905.
5
Functional models of nonheme diiron enzymes: reactivity of the μ-oxo-μ-1,2-peroxo-diiron(iii) intermediate in electrophilic and nucleophilic reactions.非血红素双铁酶的功能模型：亲电和亲核反应中μ-氧-μ-1,2-过氧-双铁(iii)中间物的反应性。
Dalton Trans. 2020 Feb 11;49(6):1742-1746. doi: 10.1039/c9dt04551a.
6
Effect of monodentate heterocycle co-ligands on the μ-1,2-peroxo-diiron(III) mediated aldehyde deformylation reactions.单核杂环共配体对 μ-1,2-过氧二铁(III)介导的醛去甲酰基反应的影响。
J Inorg Biochem. 2024 Sep;258:112620. doi: 10.1016/j.jinorgbio.2024.112620. Epub 2024 May 29.
7
Disproportionation of HO Mediated by Diiron-Peroxo Complexes as Catalase Mimics.过氧二铁配合物介导的 HO 歧化作用作为过氧化氢酶模拟物。
Molecules. 2021 Jul 26;26(15):4501. doi: 10.3390/molecules26154501.
8
Bioinspired Nonheme Iron Catalysts for C-H and C═C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants.仿生非血红素铁催化剂用于 C-H 和 C=C 键氧化：金属基氧化剂本质的深入理解。
Acc Chem Res. 2015 Sep 15;48(9):2612-21. doi: 10.1021/acs.accounts.5b00053. Epub 2015 Aug 17.
9
Functional models of nonheme diiron enzymes: kinetic and computational evidence for the formation of oxoiron(iv) species from peroxo-diiron(iii) complexes, and their reactivity towards phenols and H2O2.非血红素双铁酶的功能模型：过氧双铁（III）配合物形成氧铁（IV）物种的动力学和计算证据，以及它们对酚类和过氧化氢的反应性。
Dalton Trans. 2016 Oct 7;45(37):14709-18. doi: 10.1039/c6dt01598k. Epub 2016 Jun 10.
10
Stoichiometric Aldehyde Deformylation Mediated by Nucleophilic Peroxo-diiron(III) Complex as a Functional Model of Aldehyde Deformylating Oxygenase.亲核过氧二铁（III）配合物介导的化学计量醛去甲酰基化作为醛去甲酰化加氧酶的功能模型。
Chemistry. 2019 Nov 13;25(63):14290-14294. doi: 10.1002/chem.201903727. Epub 2019 Oct 15.

引用本文的文献

1
Effect of Substituted Pyridine Co-Ligands and (Diacetoxyiodo)benzene Oxidants on the Fe(III)-OIPh-Mediated Triphenylmethane Hydroxylation Reaction.取代吡啶共配体和（二乙酰氧基碘）苯氧化剂对Fe(III)-OIPh介导的三苯甲烷羟基化反应的影响。
Molecules. 2024 Aug 13;29(16):3842. doi: 10.3390/molecules29163842.
2
Influence of Equatorial Co-Ligands on the Reactivity of LFeOIPh.赤道面共配体对LFeOIPh反应活性的影响
Molecules. 2023 Dec 21;29(1):58. doi: 10.3390/molecules29010058.
3
Mechanisms of Sulfoxidation and Epoxidation Mediated by Iron(III)-Iodosylbenzene Adduct: Electron-Transfer vs. Oxygen-Transfer Mechanism.

本文引用的文献

1
Nonheme Diiron Oxygenase Mimic That Generates a Diferric-Peroxo Intermediate Capable of Catalytic Olefin Epoxidation and Alkane Hydroxylation Including Cyclohexane.非血红素双铁加氧酶模拟物，可生成一种双铁-过氧中间体，能够催化烯烃环氧化和烷烃羟基化反应，包括环己烷的羟基化反应。
Inorg Chem. 2022 Jan 10;61(1):37-41. doi: 10.1021/acs.inorgchem.1c03468. Epub 2021 Dec 11.
2
A nonheme peroxo-diiron(III) complex exhibiting both nucleophilic and electrophilic oxidation of organic substrates.一种非血红素过氧二铁（III）配合物，对有机底物同时表现出亲核氧化和亲电氧化作用。
Dalton Trans. 2021 Jun 1;50(21):7181-7185. doi: 10.1039/d1dt01502h.
3
铁(III)-碘代苯加合物介导的硫氧化和环氧化的机制：电子转移与氧转移机制。
Molecules. 2023 Jun 13;28(12):4745. doi: 10.3390/molecules28124745.
4
Stoichiometric Alkane and Aldehyde Hydroxylation Reactions Mediated by In Situ Generated Iron(III)-Iodosylbenzene Adduct.原位生成的铁(III)-碘代苯加合物介导的烷烃和醛的计量羟化反应。
Molecules. 2023 Feb 15;28(4):1855. doi: 10.3390/molecules28041855.
Functional models of nonheme diiron enzymes: reactivity of the μ-oxo-μ-1,2-peroxo-diiron(iii) intermediate in electrophilic and nucleophilic reactions.
非血红素双铁酶的功能模型：亲电和亲核反应中μ-氧-μ-1,2-过氧-双铁(iii)中间物的反应性。
Dalton Trans. 2020 Feb 11;49(6):1742-1746. doi: 10.1039/c9dt04551a.
4
Stoichiometric Aldehyde Deformylation Mediated by Nucleophilic Peroxo-diiron(III) Complex as a Functional Model of Aldehyde Deformylating Oxygenase.亲核过氧二铁（III）配合物介导的化学计量醛去甲酰基化作为醛去甲酰化加氧酶的功能模型。
Chemistry. 2019 Nov 13;25(63):14290-14294. doi: 10.1002/chem.201903727. Epub 2019 Oct 15.
5
Transition Metal Catalysis in the Baeyer-Villiger Oxidation of Ketones.过渡金属催化的酮的拜耳-维利格氧化反应
Angew Chem Int Ed Engl. 1998 May 18;37(9):1198-1209. doi: 10.1002/(SICI)1521-3773(19980518)37:9<1198::AID-ANIE1198>3.0.CO;2-Y.
6
Flexibility and lability of a phenyl ligand in hetero-organometallic 3d metal-Sn(iv) compounds and their catalytic activity in Baeyer-Villiger oxidation of cyclohexanone.杂有机金属3d金属-Sn(IV)化合物中苯基配体的灵活性和活性及其在环己酮的拜耳-维利格氧化反应中的催化活性
Dalton Trans. 2017 Oct 10;46(39):13364-13375. doi: 10.1039/c7dt02534c.
7
Functional models of nonheme diiron enzymes: kinetic and computational evidence for the formation of oxoiron(iv) species from peroxo-diiron(iii) complexes, and their reactivity towards phenols and H2O2.非血红素双铁酶的功能模型：过氧双铁（III）配合物形成氧铁（IV）物种的动力学和计算证据，以及它们对酚类和过氧化氢的反应性。
Dalton Trans. 2016 Oct 7;45(37):14709-18. doi: 10.1039/c6dt01598k. Epub 2016 Jun 10.
8
Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands.用非对称双齿氮供体配体稳定μ-过氧桥联铁(III)中间体
Chem Commun (Camb). 2014 Feb 9;50(11):1326-9. doi: 10.1039/c3cc48196d.
9
Arabidopsis CYP85A2, a cytochrome P450, mediates the Baeyer-Villiger oxidation of castasterone to brassinolide in brassinosteroid biosynthesis.拟南芥细胞色素P450 CYP85A2在油菜素甾醇生物合成过程中，介导了从castasterone到油菜素内酯的拜耳-维利格氧化反应。
Plant Cell. 2005 Aug;17(8):2397-412. doi: 10.1105/tpc.105.033738. Epub 2005 Jul 15.
10
Baeyer-Villiger oxidation in compressed CO2.在压缩二氧化碳中的拜耳-维立格氧化反应。
Chem Commun (Camb). 2002 Aug 7(15):1588-9. doi: 10.1039/b202727e.