Hynes Navasingh Rajesh Jesudoss, Vignesh Nagarajan Jawahar, Barile Claudia, Velu Pitchumani Shenbaga, Baskaran Thangagiri, Jappes Jebas Thangiah Winowlin, Al-Khashman Omar Ali, Brykov Michail, Ene Antoaneta
Department of Mechanical Engineering, Mepco Schlenk Engineering College, Sivakasi 626005, Virudhunagar, India.
Dipartimento di Meccanica, Matematica e Management, Politecnico di Bari, Viale Japigia 182, 70126 Bari, Italy.
Polymers (Basel). 2022 Apr 21;14(9):1700. doi: 10.3390/polym14091700.
Aluminium-based fibre-metal laminates are lucrative candidates for aerospace manufacturers since they are lightweight and high-strength materials. The flower extract of aerva lanata was studied in order to prevent the effect of corrosion on the aluminium-based fibre-metal laminates (FMLs) in basic media. It is considered an eco-friendly corrosion inhibitor using natural sources. Its flower species belong to the Amaranthaceae family. The results of the Fourier-transform infrared spectroscopy (FTIR) show that this flower extract includes organic compounds such as aromatic links, heteroatoms, and oxygen, which can be used as an organic corrosion inhibitor in an acidic environment. The effectiveness of the aerva-lanata flower behaviour in acting as an inhibitor of the corrosion process of FMLs was studied in 3.5% NaCl solution. The inhibition efficiency was calculated within a range of concentration of the inhibitor at room temperature, using the weight-loss method, potentiodynamic polarization measurements and electrochemical-impedance spectroscopy (EIS). The results indicate a characterization of about 87.02% in the presence of 600 ppm of inhibitor. The Tafel curve in the polarization experiments shows an inhibition efficiency of 88%. The inhibition mechanism was the absorption on the FML surface, and its absorption was observed with the aid of the Langmuir adsorption isotherm. This complex protective film occupies a larger surface area on the surface of the FML. Hence, by restricting the surface of the metallic layer from the corrosive medium, the charge and ion switch at the FML surface is reduced, thereby increasing the corrosion resistance.
铝基纤维金属层压板是航空航天制造商的理想选择,因为它们是轻质且高强度的材料。对白花蛇舌草的花提取物进行了研究,以防止碱性介质对铝基纤维金属层压板(FMLs)的腐蚀作用。它被认为是一种使用天然来源的环保型缓蚀剂。其花种属于苋科。傅里叶变换红外光谱(FTIR)结果表明,这种花提取物含有芳香键、杂原子和氧等有机化合物,可在酸性环境中用作有机缓蚀剂。在3.5%氯化钠溶液中研究了白花蛇舌草花提取物对FMLs腐蚀过程的缓蚀效果。在室温下,使用失重法、动电位极化测量和电化学阻抗谱(EIS),在缓蚀剂浓度范围内计算缓蚀效率。结果表明,在存在600 ppm缓蚀剂的情况下,缓蚀率约为87.02%。极化实验中的塔菲尔曲线显示缓蚀效率为88%。缓蚀机理是在FML表面吸附,借助朗缪尔吸附等温线观察到其吸附情况。这种复合保护膜在FML表面占据更大的表面积。因此,通过限制金属层表面与腐蚀介质接触,减少了FML表面的电荷和离子交换,从而提高了耐腐蚀性。