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用于金属及合金在与盐水接触时防护的绿色缓蚀剂

Green Corrosion Inhibitors for Metal and Alloys Protection in Contact with Aqueous Saline.

作者信息

Galleguillos Madrid Felipe M, Soliz Alvaro, Cáceres Luis, Bergendahl Markus, Leiva-Guajardo Susana, Portillo Carlos, Olivares Douglas, Toro Norman, Jimenez-Arevalo Victor, Páez Maritza

机构信息

Centro de Desarrollo Energético de Antofagasta, Universidad de Antofagasta, Av. Universidad de Antofagasta 02800, Antofagasta 1271155, Chile.

Departamento de Ingeniería en Metalurgia, Universidad de Atacama, Av. Copayapu 485, Copiapó 1530000, Chile.

出版信息

Materials (Basel). 2024 Aug 11;17(16):3996. doi: 10.3390/ma17163996.

DOI:10.3390/ma17163996
PMID:39203174
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11356518/
Abstract

Corrosion is an inevitable and persistent issue that affects various metallic infrastructures, leading to significant economic losses and safety concerns, particularly in areas near or in contact with saline solutions such as seawater. Green corrosion inhibitors are compounds derived from natural sources that are biodegradable in various environments, offering a promising alternative to their conventional counterparts. Despite their potential, green corrosion inhibitors still face several limitations and challenges when exposed to NaCl environments. This comprehensive review delves into these limitations and associated challenges, shedding light on the progress made in addressing these issues and potential future developments as tools in corrosion management. Explicitly the following aspects are covered: (1) attributes of corrosion inhibitors, (2) general corrosion mechanism, (3) mechanism of corrosion inhibition in NaCl, (4) typical electrochemical and surface characterization techniques, (5) theoretical simulations by Density Functional Theory, and (6) corrosion testing standards and general guidelines for corrosion inhibitor selection. This review is expected to advance the knowledge of green corrosion inhibitors and promote further research and applications.

摘要

腐蚀是一个不可避免且长期存在的问题，它影响着各种金属基础设施，导致重大的经济损失和安全隐患，尤其是在靠近海水或与海水接触的区域。绿色缓蚀剂是源自天然来源的化合物，在各种环境中均可生物降解，是传统缓蚀剂的一种有前景的替代品。尽管具有潜力，但绿色缓蚀剂在暴露于氯化钠环境时仍面临一些限制和挑战。这篇综述深入探讨了这些限制和相关挑战，阐明了在解决这些问题方面取得的进展以及作为腐蚀管理工具的潜在未来发展。具体涵盖以下几个方面：（1）缓蚀剂的属性，（2）一般腐蚀机制，（3）在氯化钠中的缓蚀机制，（4）典型的电化学和表面表征技术，（5）密度泛函理论的理论模拟，以及（6）腐蚀测试标准和缓蚀剂选择的一般指南。预计这篇综述将增进对绿色缓蚀剂的了解，并促进进一步的研究和应用。

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