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具有三角形截面的三维梯度编织复合材料的电磁波吸收与弯曲特性

Electromagnetic Wave-Absorbing and Bending Properties of Three-Dimensional Gradient Woven Composites with Triangular Sections.

作者信息

Zhang Huawei, Zhou Xinghai, Gao Yuan, Wang Ying, Liao Yongping, Wu Liwei, Lyu Lihua

机构信息

School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, China.

Ministry of Education Key Laboratory for Advanced Textile Composite Materials, Tiangong University, Tianjin 300387, China.

出版信息

Polymers (Basel). 2022 Apr 25;14(9):1745. doi: 10.3390/polym14091745.

Abstract

In order to solve defects such as poor integrity, delamination failure, and narrow absorption bandwidth, three-dimensional (3D) gradient honeycomb woven composites (GHWCs) with triangular sections were designed and prepared. Three-dimensional gradient honeycomb woven fabric was crafted with carbon fiber (CF) filaments and basalt fiber (BF) filaments as raw materials on an ordinary loom. Then, the 3D honeycomb woven fabric filled with rigid polyurethane foam was used as the reinforcement, and epoxy resin (EP) doped with carbon black (CB) and carbonyl iron powder (CIP) was conducted as the matrix. The 3D GHWC with triangular sections, which had both EM-absorbing and load-bearing functions, was prepared by the VARTM process. Through the macro test and micro characterization of 3D GHWCs with triangular sections, the overall absorbing properties and mechanical properties of the materials were analyzed. Moreover, the EM-absorbing mechanism and failure mode of the materials were clarified in this work. The results indicated that the CF filament reflective layer effectively improved the EM-absorbing and mechanical properties. Adding a CB/CIP-absorbing agent enhanced the overall EM-absorbing property but reduced the mechanical properties. The increasing number of gradient layers increased the maximum bending load, but the EM-absorbing performance first increased and then decreased. When the thickness was 15 mm, the maximum bending load was 3530 N, and the minimum reflection loss (RL) was -21.6 dB. The synergistic effects of EM-absorbing and mechanical properties were the best right now. In addition, this work provided a feasible strategy that adjusting the type of absorber and gradient aperture size ratio could meet the unique requirements of absorbing frequency and intensity, which has excellent application prospects in civil and military fields.

摘要

为了解决诸如整体性差、分层破坏和吸收带宽窄等缺陷,设计并制备了具有三角形截面的三维(3D)梯度蜂窝编织复合材料(GHWC)。以碳纤维(CF)长丝和玄武岩纤维(BF)长丝为原料,在普通织机上织造三维梯度蜂窝织物。然后,以填充有硬质聚氨酯泡沫的3D蜂窝织物为增强体,以掺杂有炭黑(CB)和羰基铁粉(CIP)的环氧树脂(EP)为基体。通过真空辅助树脂传递模塑(VARTM)工艺制备了兼具吸波和承载功能的具有三角形截面的3D GHWC。通过对具有三角形截面的3D GHWC进行宏观测试和微观表征,分析了材料的整体吸波性能和力学性能。此外,在本工作中阐明了材料的吸波机理和失效模式。结果表明,CF长丝反射层有效地提高了吸波性能和力学性能。添加CB/CIP吸收剂提高了整体吸波性能,但降低了力学性能。梯度层数的增加提高了最大弯曲载荷,但吸波性能先增加后降低。当厚度为15 mm时,最大弯曲载荷为3530 N,最小反射损耗(RL)为-21.6 dB。此时吸波性能和力学性能的协同效应最佳。此外,本工作提供了一种可行的策略,即调整吸收剂类型和梯度孔径尺寸比可以满足吸波频率和强度的独特要求,在民用和军事领域具有优异的应用前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9469/9100788/19c6b1f12124/polymers-14-01745-g009.jpg

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