Center for Multidimensional Carbon Materials (CMCM), Institute for Basic Science (IBS), Ulsan, 44919, Republic of Korea.
Department of Chemistry, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, Republic of Korea.
Chem Commun (Camb). 2022 Jun 1;58(45):6498-6501. doi: 10.1039/d2cc01908f.
A novel 2 : 1 host-guest complex forms between 8--butyl-6-azapenta-benzo[,,,,]corannulene (1) and C with positive cooperativity ( = 2.56) and high affinity ( × = 2.8 × 10 M) at 25 °C. The C undergoes increasing shape complementarity toward 1 throughout the binding process.
在 25°C 下，8--正丁基-6-氮杂五苯并[,,,,]corannulene（1）和 C 之间形成了一种新颖的 2:1 主客体配合物，具有正协同性（ = 2.56）和高亲和力（× = 2.8×10 M）。在整个结合过程中，C 逐渐对 1 产生越来越大的形状互补性。
