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先进锂原电池:关键材料、研究进展与挑战

Advanced Lithium Primary Batteries: Key Materials, Research Progresses and Challenges.

作者信息

Liu Yan, Su Meng-Yuan, Gu Zhen-Yi, Zhang Kai-Yang, Wang Xiao-Tong, Du Miao, Guo Jin-Zhi, Wu Xing-Long

机构信息

Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024, P.R. China.

MOE Key Laboratory for UV Light-Emitting Materials and Technology, Northeast Normal University, Changchun, Jilin 130024, P.R. China.

出版信息

Chem Rec. 2022 Oct;22(10):e202200081. doi: 10.1002/tcr.202200081. Epub 2022 May 18.

DOI:10.1002/tcr.202200081
PMID:35585030
Abstract

In recent years, with the vigorous development and gradual deployment of new energy vehicles, more attention has been paid to the research on lithium-ion batteries (LIBs). Compared with the booming LIBs, lithium primary batteries (LPBs) own superiority in specific energy and self-discharge rate and are usually applied in special fields such as medical implantation, aerospace, and military. Widespread application in special fields also means more stringent requirements for LPBs in terms of energy density, working temperature range and shelf life. Therefore, how to obtain LPBs with high energy density, wide operational temperature range and long storage life is of great importance in future development. In view of the above, this paper reviews the latest research on LPBs in cathode, anode and electrolyte over the years, and puts forward relevant insights for LPBs, along with the intention to explore avenues for the design of LPBs components in the coming decades and promote further development in this field.

摘要

近年来,随着新能源汽车的蓬勃发展和逐步推广,锂离子电池(LIBs)的研究受到了更多关注。与蓬勃发展的锂离子电池相比,锂原电池(LPBs)在比能量和自放电率方面具有优势,通常应用于医疗植入、航空航天和军事等特殊领域。在特殊领域的广泛应用也意味着对锂原电池在能量密度、工作温度范围和保质期方面有更严格的要求。因此,如何获得具有高能量密度、宽工作温度范围和长储存寿命的锂原电池在未来发展中至关重要。鉴于此,本文综述了多年来锂原电池在正极、负极和电解质方面的最新研究,并对锂原电池提出了相关见解,旨在探索未来几十年锂原电池组件的设计途径,推动该领域的进一步发展。

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引用本文的文献

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Materials (Basel). 2023 Jun 8;16(12):4266. doi: 10.3390/ma16124266.
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Two-Dimensional Iron Phosphorus Trisulfide as a High-Capacity Cathode for Lithium Primary Battery.二维铁磷三硫化物作为锂一次电池的高容量正极。
Molecules. 2023 Jan 5;28(2):537. doi: 10.3390/molecules28020537.