Yu Hao, Lin Yu-Diao, Liu Zheng-Yi, Sun Yan-Qiong, Zheng Shou-Tian
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China.
Inorg Chem. 2022 May 30;61(21):8112-8116. doi: 10.1021/acs.inorgchem.2c00705. Epub 2022 May 19.
A rare 3D Indium-containing polyoxoniobate framework {H[Cu(en)(HO)][Cu(en)][In(en)][Nb-O(OH)(HO)]{NbO(OH)(HO)]}·68HO(), based on the In-containing polyoxoniobate cluster, {[In(en)][NbO(OH)(HO)][NbO(OH)(HO)]} ({InNb}) and [Cu(en)] linkers has been successfully synthesized. The nest-like cluster {InNb} is constructed from one brand-new V-shaped {NbO}, two triangle-shaped {NbO} and five [In(en)]. The [In(en)] fragments link {NbO} and {NbO} units into unique {InNb} helical pillars. The copper-amine complexes connect the {InNb} helical pillars into a three-dimensional (3D) inorganic-organic hybrid In-Cu-containing framework. This material also exhibits good ionic conductivity and vapor adsorption capacity properties.
一种基于含铟多铌酸盐簇{[In(en)][NbO(OH)(HO)][NbO(OH)(HO)]}（{InNb}）和[Cu(en)]连接体的罕见三维含铟多铌酸盐骨架{H[Cu(en)(HO)][Cu(en)][In(en)][Nb - O(OH)(HO)]{NbO(OH)(HO)]}·68HO()已成功合成。巢状簇{InNb}由一个全新的V形{NbO}、两个三角形{NbO}和五个[In(en)]构建而成。[In(en)]片段将{NbO}和{NbO}单元连接成独特的{InNb}螺旋柱。铜 - 胺配合物将{InNb}螺旋柱连接成三维（3D）无机 - 有机杂化含铟 - 铜骨架。该材料还表现出良好的离子传导性和蒸汽吸附容量特性。
