Using sp N atom anchoring effect to prepare ultrafine vanadium nitride particles on porous nitrogen-doped carbon as cathode for lithium-sulfur battery.

Porous carbon-supported transition metals and their compounds have attracted much attention as sulfur host materials for cathodes of lithium-sulfur batteries, due to their high chemisorption capacity and ability to catalyze the conversion of polysulfides. However, actual activity of these materials is not very high because of low specific surface areas of transition metal compounds synthesized at high temperatures. In this study, ultra-fine vanadium nitride particles with an average particle size of ca. 4 nm (VN/M/NC) are successfully grown on the surface of nitrogen-doped three-dimensional carbon using sp nitrogen atoms, resulting from melamine pyrolysis in the presence of ammonium metavanadate, as anchor points to lock vanadium atoms in the VN/M/NC material. When used as a cathode for lithium-sulfur battery, VN/M/NC demonstrates initial discharge specific capacity of 1080 mAh g at 0.2 C, and retains a discharge capacity of 475 mAh g at a high rate of 2 C. With capacity attenuation of only 0.037% per cycle after 500 cycles at 1 C, the newly obtained VN/M/NC can be a promising cathode material for lithium-sulfur batteries.