Vis Mark, Opdam Joeri, van 't Oor Ingo S J, Soligno Giuseppe, van Roij René, Tromp R Hans, Erné Ben H
Van 't Hoff Laboratory for Physical and Colloid Chemistry, Debye Institute for Nanomaterials Science, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands.
Institute for Theoretical Physics, Center for Extreme Matter and Emergent Phenomena, Utrecht University, Leuvenlaan 4, 3584 CE Utrecht, The Netherlands.
ACS Macro Lett. 2015 Sep 15;4(9):965-968. doi: 10.1021/acsmacrolett.5b00480. Epub 2015 Sep 2.
Ultrathin plate-like colloidal particles are effective candidates for Pickering stabilization of water-in-water emulsions, a stabilization that is complicated by the thickness and ultralow tension of the water-water interface. Plate-like particles have the advantage of blocking much of the interface while simultaneously having a low mass. Additionally, the amount of blocked interface is practically independent of the equilibrium contact angle θ at which the water-water interface contacts the nanoplates. As a result, the adsorption of nanoplates is stronger than for spheres with the same maximal cross section, except if θ = 90°.
超薄片状胶体颗粒是水包水乳液皮克林稳定化的有效候选物,这种稳定化因水-水界面的厚度和超低张力而变得复杂。片状颗粒具有阻挡大部分界面的优点,同时质量较低。此外,被阻挡的界面量实际上与水-水界面与纳米板接触时的平衡接触角θ无关。因此,除了θ = 90°的情况外,纳米板的吸附比具有相同最大横截面的球体更强。