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高效提取生物柴油原料和脱水厨余垃圾:基于液化二甲醚和水共溶解的方法。

Efficient extraction of biodiesel feedstock and dehydration of kitchen waste: A method based on co-dissolution of liquefied dimethyl ether and water.

机构信息

College of Environment, Hohai University, Nanjing 210098, China.

College of Environment, Hohai University, Nanjing 210098, China; Taihu Lake Research Center, Institute of Water Science and Technology, Hohai University, Nanjing 210098, China.

出版信息

Waste Manag. 2022 Jun 15;147:22-29. doi: 10.1016/j.wasman.2022.04.044. Epub 2022 May 18.

Abstract

In the context of low-carbon development, as a waste rich in lipids, kitchen waste (KW) has received increasing attention for resource utilization and low-carbon utilization. In this study, we explored a method for efficient extraction of lipids and dehydration using liquefied dimethyl ether (L-DME) to address the problem of high lipids and the difficulty of dewatering of KW. A closed DME reaction vessel was used to conduct experiments on the effects of lipids extraction and dehydration of KW under different reaction times, mass ratios, temperatures and moisture contents. It was found that DME could extract more than 90% of the lipids and the dehydration rate could reach approximately 80%. The main components of the lipids in the liquid phase extract were fatty acids (C18:2, C18:1, C16:0, and C18:0) whose good thermal properties made them suitable for use as a feedstock for biodiesel production. Moreover, the greatly increased heating value of the solid residue facilitated low-carbon utilization. This study also demonstrated a promotion effect of the co-dissolution system of L-DME and water on the extraction of lipids and explored the related mechanism.

摘要

在低碳发展的背景下,厨余垃圾(KW)作为一种富含油脂的废弃物,其资源利用和低碳利用受到了越来越多的关注。本研究探索了一种使用液化二甲醚(L-DME)高效提取油脂和脱水的方法,以解决 KW 油脂含量高和脱水困难的问题。采用封闭的 DME 反应釜,在不同反应时间、质量比、温度和水分含量下,对 KW 的油脂提取和脱水效果进行了实验。结果表明,DME 可以提取超过 90%的油脂,脱水率可达 80%左右。液相萃取中油脂的主要成分是脂肪酸(C18:2、C18:1、C16:0 和 C18:0),其良好的热性能使其适合用作生物柴油生产的原料。此外,固体残渣的高热值也有利于低碳利用。本研究还证明了 L-DME 和水的共溶解体系对油脂提取的促进作用,并探讨了相关机制。

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