Yang Fan, Zhu Yuxing, Wang Xinyi, Sun Jipeng, Wang Xin, Qian Yongjin, Wang Lu, Zhu Wei
College of Civil and Transportation Engineering, Hohai University, Nanjing 210098, China.
Key Laboratory of Ministry of Education for Geomechanics and Embankment Engineering, Hohai University, Nanjing 210098, China.
ACS Omega. 2025 Apr 9;10(15):14581-14592. doi: 10.1021/acsomega.4c06638. eCollection 2025 Apr 22.
In response to high steam usage, significant greenhouse gas emissions, and secondary pollution risks associated with solvents in steam-assisted gravity drainage (SAGD) and solvent-assisted SAGD techniques for oil sands extraction, a new technology using liquid dimethyl ether (DME) for displacement-dissolution-permeation extraction (DME-DDP) has been proposed. Using a self-designed DME-DDP experimental apparatus, oil extraction experiments were conducted on consolidated oil sands samples to simulate the oil sand formations in the Athabasca region in Canada. The experimental results indicated that oil washing efficiency reached 84% under the optimal pressure gradient, with recoveries of >90% for saturates and aromatics, >60% for resins, and >50% for asphaltenes. The DME-DDP oil extraction process includes two stages, displacement and dissolution-permeation, each contributing to approximately 50% of the total oil recovery. The pressure gradient is the primary factor influencing oil washing efficiency, with higher recovery necessitating slower permeation or extended contact time between DME and crude oil in the formation. DME is a colorless, nontoxic, and nongreenhouse gas that can be recycled. These characteristics underscore the environmental sustainability and cost-effectiveness of the proposed method.
针对蒸汽辅助重力泄油(SAGD)和溶剂辅助SAGD油砂开采技术中蒸汽使用量大、温室气体排放显著以及与溶剂相关的二次污染风险问题,提出了一种使用液态二甲醚(DME)进行驱替-溶解-渗透萃取(DME-DDP)的新技术。利用自行设计的DME-DDP实验装置,对固结油砂样品进行了油萃取实验,以模拟加拿大阿萨巴斯卡地区的油砂地层。实验结果表明,在最佳压力梯度下,洗油效率达到84%,饱和烃和芳烃回收率>90%,树脂回收率>60%,沥青质回收率>50%。DME-DDP油萃取过程包括驱替和溶解-渗透两个阶段,每个阶段对总油回收率的贡献约为50%。压力梯度是影响洗油效率的主要因素,回收率越高,DME在地层中与原油的渗透速度越慢或接触时间越长。DME是一种无色、无毒且无温室气体排放的物质,可循环利用。这些特性突出了该方法的环境可持续性和成本效益。