Kikuchi Kei, Iwasawa Akari, Omori Mitsuki, Mayama Hiroyuki, Nonomura Yoshimune
Department of Biochemical Engineering, Graduate School of Science and Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa 992-8510, Japan.
Department of Chemistry, Asahikawa Medical University, 2-1-1-1 Midorigaoka-Higashi, Asahikawa 078-8510, Japan.
ACS Omega. 2022 May 3;7(19):16515-16523. doi: 10.1021/acsomega.2c00677. eCollection 2022 May 17.
Foams are viscoelastic soft materials with complex mechanical properties. Here, we evaluated the friction dynamics of foams between acrylic plates using a sinusoidal motion friction evaluation system and we found some interesting characteristics under accelerated conditions. On a typical solid surface, a symmetrical friction profile, in which static and kinetic frictions are observed, is obtained under reciprocating nonlinear motion. Meanwhile, significant lubricant effects and velocity-dependent friction profiles without static friction were observed in foams. The friction force in foams increased in proportion to the power of velocity, with a power index of <1. These characteristic and dynamic phenomena in foams were observed in this study. They had been caused by the formation of a thick lubricant film and various dissipative modes including surfactant diffusion, viscous dissipation, and wall slip of bubbles. Moreover, the addition of a thickener increased the friction force and the delay time of friction response and improved the foam durability against normal force and shear. These findings are useful for understanding dynamic phenomena in soft materials.
泡沫材料是具有复杂力学性能的粘弹性软材料。在此,我们使用正弦运动摩擦评估系统评估了丙烯酸板之间泡沫材料的摩擦动力学,并在加速条件下发现了一些有趣的特性。在典型的固体表面上,在往复非线性运动下可获得一个对称的摩擦曲线,其中观察到静摩擦和动摩擦。同时,在泡沫材料中观察到了显著的润滑效应和与速度相关的摩擦曲线,且不存在静摩擦。泡沫材料中的摩擦力与速度的幂成正比,幂指数小于1。本研究中观察到了泡沫材料中的这些特征和动态现象。它们是由厚润滑膜的形成以及包括表面活性剂扩散、粘性耗散和气泡壁滑移在内的各种耗散模式引起的。此外,添加增稠剂会增加摩擦力和摩擦响应的延迟时间,并提高泡沫材料抵抗法向力和剪切力的耐久性。这些发现有助于理解软材料中的动态现象。