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城市固体废弃物焚烧底灰(MSWIBA)在可持续混凝土中的新型回收利用应用。

Novel recycling application of high volume municipal solid waste incineration bottom ash (MSWIBA) into sustainable concrete.

作者信息

Liu Jun, Fan Xu, Li Zhenlin, Zhang Weizhuo, Jin Hesong, Xing Feng, Tang Luping

机构信息

Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, College of Civil and Transportation Engineering, Shenzhen University, Shenzhen 518060, PR China.

Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, College of Civil and Transportation Engineering, Shenzhen University, Shenzhen 518060, PR China.

出版信息

Sci Total Environ. 2022 Sep 10;838(Pt 2):156124. doi: 10.1016/j.scitotenv.2022.156124. Epub 2022 May 20.

Abstract

Since municipal solid waste incineration bottom ash (MSWIBA) contains some heavy metals that are harmful to the groundwater and soil, this study proposes an effective and new approach to deal with high-volume MSWIBA. Selecting 70% MSWIBA, 10% ordinary Portland cement (OPC), 10% fly ash/ground granulated blast furnace slag (FA/GGBFS), and 1% volume of polypropylene (PP) fiber as the raw materials, this project designed and manufactured cold-bonded fiber aggregates (CBFAs) and applied them into sustainable concrete. It was found that the water absorption of CBFAs was between 12 and 14%, the bulk density was between 900 and 1100 kg/m, and the compressive strength of single particle was greater than 1.8 MPa. And it was found that the mechanical strength and bulk density of CBFAs were positively correlated, while the mechanical strength and water absorption were negatively correlated. The leaching behaviors of CBFAs on Cu, Pb, Cd, and Cr were successfully suppressed to less than 1% of that originally from MSWIBA, which can be in line with the Chinese standards. Additionally, it is also found that the green concrete with adding GGBFS-CBFAs has higher overall fluidity and better mechanical properties than the concrete with FA-CBFAs. The mechanical properties of concrete were the best under the replacement rate of 60% of CFBAs, and the strength of green concrete added with GGBFS-CBFAs reached 96% of that of ordinary concrete. In this study, the rapid chloride ion penetration test, mercury intrusion and electron microscope tests found that the bonding effect between the CBFAs and the green concrete matrix was better, and the pore structure in the transition zone of the surrounding interface was refined. The proportion of transition pores in the pore structure was up to 59%. This shows that the concrete added with CBFAs has better resistance to chloride ion diffusion, and has some improvement on the durability. This research suggests that CBFAs including high volume MSWIBA has the potential to be successfully applied as the alternative to natural aggregates in sustainable concrete, and this can also advance waste recycling, and solidify high volume heavy metals in infrastructures.

摘要

由于城市固体废弃物焚烧底灰(MSWIBA)含有一些对地下水和土壤有害的重金属,本研究提出了一种有效处理大量MSWIBA的新方法。该项目选用70%的MSWIBA、10%的普通硅酸盐水泥(OPC)、10%的粉煤灰/磨细粒化高炉矿渣(FA/GGBFS)以及1%体积的聚丙烯(PP)纤维作为原材料,设计并制造了冷粘结纤维骨料(CBFAs),并将其应用于可持续混凝土中。研究发现,CBFAs的吸水率在12%至14%之间,堆积密度在900至1100kg/m之间,单颗粒抗压强度大于1.8MPa。并且发现CBFAs的机械强度与堆积密度呈正相关,而机械强度与吸水率呈负相关。CBFAs对铜、铅、镉和铬的浸出行为成功抑制至低于MSWIBA原浸出量的1%,符合中国标准。此外,还发现添加GGBFS-CBFAs的绿色混凝土比添加FA-CBFAs的混凝土具有更高的整体流动性和更好的力学性能。当CBFAs替代率为60%时,混凝土的力学性能最佳,添加GGBFS-CBFAs的绿色混凝土强度达到普通混凝土的96%。在本研究中,快速氯离子渗透试验、压汞试验和电子显微镜试验发现,CBFAs与绿色混凝土基体之间的粘结效果较好,周围界面过渡区的孔隙结构得到细化。孔隙结构中过渡孔的比例高达59%。这表明添加CBFAs的混凝土具有更好的抗氯离子扩散性能,对耐久性有一定改善。本研究表明,包含大量MSWIBA的CBFAs有潜力成功替代天然骨料应用于可持续混凝土中,这也有助于推进废物回收利用,并在基础设施中固化大量重金属。

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