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将硫铝酸钙水泥用作波特兰水泥的替代品,用于将城市固体废物焚烧底灰在灰浆中再循环。

The use of calcium sulfo-aluminate cement as an alternative to Portland Cement for the recycling of municipal solid waste incineration bottom ash in mortar.

机构信息

Faculty of Engineering, University of Balamand, UOB, Al Koura, Lebanon.

Université de Lille, ULR 4515 - LGCgE, Laboratoire de Génie Civil et géo-Environnement, F-59000 Lille, France.

出版信息

Waste Manag Res. 2020 Aug;38(8):868-875. doi: 10.1177/0734242X20925170. Epub 2020 May 18.

Abstract

Municipal solid waste incineration generates large quantities of bottom ash that should be recycled. Current use of municipal solid waste incineration bottom ash (MSWI-BA) in cementitious materials is mostly in Ordinary Portland Cement (OPC). This paper considers using MSWI-BA as sand substitution in Calcium Sulfoaluminate Cement (CSA) as an alternative to OPC. A comparison between OPC and CSA mortars containing 0-2 mm MSWI-BA is conducted. The MSWI-BA used was treated to remove the ferrous and non-ferrous metals in order to obtain a better mineral fraction. Different percentages (0%, 25%, 50%, 75%, and 100%) of standard sand were substituted by MSWI-BA based on equivalent volume. Experimental results showed that the compressive strength and porosity of the CSA mortars were superior to OPC after substitution at 1, 7, 28, and 90 days. The compressive strength of OPC mortars with 25% substitution decreased by 40% compared to 11% for CSA mortars at 90 days. This is due to the difference in pH between the two cement pastes as OPC in contact with the MSWI-BA leads to a reaction with the aluminum content which releases hydrogen gas, increases the porosity, and decreases the compressive strength.

摘要

城市生活垃圾焚烧产生大量底灰,应加以回收利用。目前,城市生活垃圾焚烧底灰(MSWI-BA)在胶凝材料中的应用主要是在普通波特兰水泥(OPC)中。本文考虑将 MSWI-BA 用作钙硫铝酸盐水泥(CSA)中的砂替代物,以替代 OPC。对含有 0-2mm MSWI-BA 的 OPC 和 CSA 砂浆进行了比较。所使用的 MSWI-BA 经过处理以去除铁和有色金属,以获得更好的矿物组分。基于体积等效,用 MSWI-BA 替代了不同百分比(0%、25%、50%、75%和 100%)的标准砂。实验结果表明,在替代后 1、7、28 和 90 天,CSA 砂浆的抗压强度和孔隙率均优于 OPC。与 CSA 砂浆相比,90 天时替代 25%的 OPC 砂浆的抗压强度下降了 40%。这是由于两种水泥浆之间的 pH 值不同,因为与 MSWI-BA 接触的 OPC 会与铝含量发生反应,释放氢气,增加孔隙率,降低抗压强度。

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