Mao Chaoying, Kong Miqiu, Yang Qi, Li Guangxian, Huang Yajiang
College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering of China, Sichuan University, Chengdu 610065, China.
ACS Macro Lett. 2016 Aug 16;5(8):900-903. doi: 10.1021/acsmacrolett.6b00456. Epub 2016 Jul 13.
We study the influence of particle shape on shear-induced droplet deformation in polymeric emulsions. During shearing, droplets become elongated and rotate periodically about their major axes while aligning along the vorticity direction in ellipsoid-filled emulsions, while similar behavior is not observed in the pristine, microsphere-filled or ellipsoid-filled inverse systems. Based on the Jeffery orbit theory, the formation of anisotropic droplets with extremely small Reynolds number due to arrested coalescence in Newtonian matrix and strong confinement effect are suggested to be responsible for the vorticity alignment of droplets during slow shearing.