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具有超疏水防冰和光热除冰性能的多功能TiCT MXene基复合涂层

Multifunctional TiCT MXene-Based Composite Coatings with Superhydrophobic Anti-icing and Photothermal Deicing Properties.

作者信息

Zhao Yushun, Yan Cheng, Hou Tianqi, Dou Hongli, Shen Hao

机构信息

School of Electrical Engineering and Automation, Hefei University of Technology, Hefei 230009, China.

出版信息

ACS Appl Mater Interfaces. 2022 Jun 8;14(22):26077-26087. doi: 10.1021/acsami.2c07087. Epub 2022 May 24.

Abstract

Although advances in industrial products have brought convenience to our lives, severe weather has increased the safety risks to industrial facilities. Considerable efforts have been made to develop high-performance superhydrophobic anti-icing coatings. Nevertheless, designing a functional coating with both anti-icing properties and self-deicing remains a major challenge. Here, we propose a design strategy to exploit a photothermal superhydrophobic multifunctional coating with excellent anti-icing and deicing properties based on MXene by high-temperature sintering and layer-by-layer coating. Specifically, poly(tetrafluoroethylene) (PTFE) particles provide low surface energy and binding effects. Room-temperature-vulcanized silicone rubber (RTV) enhances the dispersion of the composite particles and the adhesion of the functional coating to a glass substrate. Furthermore, the functional coatings constructed with MXene exhibit outstanding photothermal effects, imparting excellent superhydrophobicity (CA = 160.18°, SA = 1.8°) and efficient photothermal conversion (equilibrium temperature of 109.3 °C). An anti-icing/deicing test is simulated to confirm their efficient anti-icing/deicing performance in practical applications. Overall, the functional coatings designed in this work can be applied in real industrial facilities.

摘要

尽管工业产品的进步给我们的生活带来了便利,但恶劣天气增加了工业设施的安全风险。人们已经做出了相当大的努力来开发高性能的超疏水防冰涂层。然而,设计一种兼具防冰和自除冰性能的功能性涂层仍然是一个重大挑战。在此,我们提出一种设计策略,通过高温烧结和层层涂覆,利用基于MXene的具有优异防冰和除冰性能的光热超疏水多功能涂层。具体而言,聚四氟乙烯(PTFE)颗粒提供低表面能和粘结效果。室温硫化硅橡胶(RTV)增强了复合颗粒的分散性以及功能性涂层与玻璃基板的附着力。此外,由MXene构建的功能性涂层表现出出色的光热效应,赋予其优异的超疏水性(接触角CA = 160.18°,滚动角SA = 1.8°)和高效的光热转换(平衡温度为109.3°C)。模拟了防冰/除冰测试以确认它们在实际应用中的高效防冰/除冰性能。总体而言,这项工作中设计的功能性涂层可应用于实际工业设施。

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