Wang De, Zhang Zhen, Hadjichristidis Nikos
King Abdullah University of Science and Technology (KAUST), Physical Sciences and Engineering Division, KAUST Catalysis Center, Polymer Synthesis Laboratory, Thuwal 23955, Kingdom of Saudi Arabia.
ACS Macro Lett. 2016 Mar 15;5(3):387-390. doi: 10.1021/acsmacrolett.6b00082. Epub 2016 Mar 1.
A novel arsonium ylide, ω-2-methylallylarsonium ylide, was synthesized and used as monomer for polyhomologation with triethyborane as initiator. It was found that the terminal methyl group leads to C3 polymerization. Furthermore, the copolyhomologation of arsonium ylide with dimethylsulfoxonium methylide is reported for the first time.
合成了一种新型的鏻叶立德，即ω-2-甲基烯丙基鏻叶立德，并将其用作单体，以三乙基硼烷为引发剂进行多聚同系化反应。发现末端甲基会引发C3聚合反应。此外，首次报道了鏻叶立德与二甲基亚砜甲基叶立德的共聚同系化反应。
