State Key Lab of Clean Energy Utilization, State Environmental Protection Engineering Center for Coal-Fired Air Pollution Control, Zhejiang University, 38 Zheda Road, Hangzhou 310027, P. R. China.
China University of Petroleum East China, College New Energy, Qingdao 266580, P. R. China.
Environ Sci Technol. 2022 Jun 21;56(12):8844-8853. doi: 10.1021/acs.est.2c00917. Epub 2022 May 27.
Pollutant removal and resource recovery from high-humidity flue gas after desulfurization in a thermal power plant are crucial for improving air quality and saving energy. This study developed a flue gas treatment method involving phase transition enhanced by corona discharge based on laboratory research and established a field-scale unit for demonstration. The results indicate that an adequate increase in size will improve the ease of particle capture. A wet electrostatic precipitator is applied before the condensing heat exchangers to enhance the particle growth and capture processes. This results in an increase of 58% in the particle median diameter in the heat exchanger and an emission concentration below 1 mg/m. Other pollutants, such as SO and Hg, can also be removed with emission concentrations of 0.13 mg/m and 1.10 μg/m, respectively. Under the condensation enhancement of the method, it is possible to recover up to 3.26 t/h of water from 200 000 m/h saturated flue gas (323 K), and the quality of the recovered water meets the standards stipulated in China. Additionally, charge-induced condensation is shown to improve heat recovery, resulting in the recovery of more than 43.34 kJ/h·m of heat from the flue gas. This method is expected to save 2628 t of standard coal and reduce carbon dioxide emission by 2% annually, contributing to environmental protection and global-warming mitigation.
从火电厂脱硫后高湿度烟道气中去除污染物并回收资源对于改善空气质量和节约能源至关重要。本研究基于实验室研究开发了一种基于电晕放电增强的相变的烟道气处理方法,并建立了现场规模的示范装置。结果表明,适当增加尺寸将有助于提高颗粒捕集的便利性。在凝结式换热器前应用湿式静电除尘器,以增强颗粒生长和捕集过程。这导致换热器中颗粒中值直径增加了 58%,排放浓度低于 1mg/m。其他污染物,如 SO 和 Hg,排放浓度分别为 0.13mg/m 和 1.10μg/m,也可以去除。在该方法的冷凝增强作用下,从 200000m/h 饱和烟道气(323K)中可回收高达 3.26t/h 的水,回收水的质量符合中国规定的标准。此外,电荷诱导冷凝被证明可以提高热回收效率,从烟道气中回收超过 43.34kJ/h·m 的热量。该方法预计每年可节约 2628 吨标准煤,减少 2%的二氧化碳排放,有助于环境保护和减缓全球变暖。