Zhang Sheng-Nan, Pang Hao-Qiang, Fan Ting-Hui, Ye Qing, Cai Qi-Lin, Wu Xi
College of Energy, Soochow University, 333 East Ganjiang Road, Suzhou 215031, China.
School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China.
Gels. 2022 May 20;8(5):320. doi: 10.3390/gels8050320.
Silica aerogel composite is an excellent thermal insulator for spacecraft under high-temperature and complex air environments. This study intends to evaluate SiC-doped silica aerogel’s thermal insulation performance under large temperature and air pressure differences. In this paper, the hot surface’s temperature response of SiC-doped silica aerogel with different content was studied at significant temperature differences (ΔT) when pressure changes instantaneously. Their thermal insulation performance was evaluated by analyzing the influence of pressure gradients on the unsteady-state heat transfer. When the cold surface’s temperature of the specimen keeps constant at 15 °C and ΔT = 171912 K, the results demonstrate that the correlative thermal conductivities of silica aerogel with 1% and 5.84% SiC are 0.022230.04077 W·m−1·K−1 at P ≈ 10 Pa and 0.03165~0.04665 W·m−1·K−1 at P = 1 atm, respectively. The aerogel composite with 0% SiC showed the best thermal insulation performance at ΔT < 200 K and P ≈ 10 Pa, while the aerogel with 5.84% SiC became the best at ΔT > 700 K and P = 1 atm. In addition, the transient pressure decreases will significantly impair the heat transfer of the gas inside the aerogel, thereby weakening the gaseous thermal conductivity and improving the thermal insulation performance.
二氧化硅气凝胶复合材料是一种在高温和复杂空气环境下用于航天器的优异隔热材料。本研究旨在评估碳化硅掺杂二氧化硅气凝胶在大温差和气压差下的隔热性能。本文研究了在压力瞬间变化时,不同含量的碳化硅掺杂二氧化硅气凝胶在显著温差(ΔT)下热表面的温度响应。通过分析压力梯度对非稳态热传递的影响来评估其隔热性能。当试样冷表面温度保持恒定在15°C且ΔT = 171912 K时,结果表明,含1%和5.84%碳化硅的二氧化硅气凝胶在P≈10 Pa时的相关热导率分别为0.022230.04077 W·m−1·K−1,在P = 1 atm时为0.03165~0.04665 W·m−1·K−1。不含碳化硅的气凝胶复合材料在ΔT < 200 K和P≈10 Pa时表现出最佳隔热性能,而含5.84%碳化硅的气凝胶在ΔT > 700 K和P = 1 atm时成为最佳。此外,瞬态压力降低会显著削弱气凝胶内部气体的热传递,从而降低气体热导率并提高隔热性能。