The Influence of Reinforced Fibers and Opacifiers on the Effective Thermal Conductivity of Silica Aerogels.

Fiber-particle-reinforced silica aerogels are widely applied in thermal insulation. Knowing their effective thermal conductivity (ETC) and radiative characteristics under high temperatures is necessary to improve their performance. This article first analyzes the radiation characteristics of silica aerogels doped with opacifier particles and reinforced fibers, and then a universal model is established to predict the ETC. Furthermore, the impacts of different parameters of opacifier particles and reinforced fibers on the thermal insulation performance of silica aerogels are investigated. The results indicate that SiC exhibits comparatively strong absorption characteristics, making it a good alternative for opacifiers to improve thermal insulation performance under high temperatures. For the given type and volume fraction of opacifier particles, there exists an optimal diameter and volume fraction to achieve the best insulation performance of silica aerogel under a certain temperature. Considering that SiO fibers exhibit a limited extinction capability and higher conductive thermal conductivity under high temperatures, for fiber-particle-reinforced silica aerogels, it is beneficial for their insulation performance to reduce the fiber volume fraction when the required mechanical properties are satisfied.