Zhu Gengjie, Zhu Wancheng, Qi Zhaojun, Yan Baoxu, Jiang Haiqiang, Hou Chen
Center for Rock Instability and Seismicity Research, School of Resource and Civil Engineering, Northeastern University, Shenyang, 110819, China.
Backfill Engineering Laboratory, Shandong Gold Mining Technology Co., Ltd, Laizhou, 261441, China.
Environ Sci Pollut Res Int. 2022 Oct;29(49):73865-73877. doi: 10.1007/s11356-022-20331-w. Epub 2022 May 27.
In this study, a one-part alkali-activated slag (AAS) composed of ground-granulated blast furnace slag, desulfurized gypsum, and hydrated lime is proposed as alternative to cement for the production of cemented fine tailings backfill (CFTB), which is an environmentally friendly binder consisting of 93.72 wt.% industrial solid waste. Results show that AAS with 67.83 wt.% slag, 25.92 wt.% desulfurized gypsum, and 6.25 wt.% hydrated lime yields the highest strength, which is 1.7-3.2 times that of ordinary Portland cement (OPC). Aside from calcium silicate hydrate gel, appreciable quantity of ettringite characterized by interlocking needles structure and high bound water is also produced during the AAS hydration process. In addition, the hydration heat of the AAS binder is 48% less than that of OPC. Moreover, CFTB made of AAS provides better workability than that of CFTB with OPC up to 20 h. The findings of this study will contribute to the production of more cost-effective, durable, and environmental-friendly cemented fine tailings backfill.
在本研究中,提出了一种由磨细粒化高炉矿渣、脱硫石膏和熟石灰组成的单组分碱激发矿渣(AAS),以替代水泥用于制备胶结细粒尾矿充填体(CFTB),这是一种由93.72 wt.%工业固体废物组成的环保型胶凝材料。结果表明,矿渣含量为67.83 wt.%、脱硫石膏含量为25.92 wt.%、熟石灰含量为6.25 wt.%的AAS强度最高,是普通硅酸盐水泥(OPC)的1.7 - 3.2倍。除了硅酸钙水化物凝胶外,在AAS水化过程中还生成了大量具有交错针状结构和高结合水的钙矾石。此外,AAS胶凝材料的水化热比OPC低48%。而且,由AAS制成的CFTB在长达20小时内比由OPC制成的CFTB具有更好的工作性能。本研究结果将有助于生产更具成本效益、耐久性和环境友好性的胶结细粒尾矿充填体。