Fujita Hiroyuki, Michinobu Tsuyoshi
Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552, Japan.
ACS Macro Lett. 2018 Jun 19;7(6):716-719. doi: 10.1021/acsmacrolett.8b00365. Epub 2018 Jun 6.
Covalent layer-by-layer (LbL) thin films with the well-defined charge-transfer (CT) chromophores were fabricated by the highly efficient [2 + 2] cycloaddition-retroelectrocyclization (CA-RE) reaction between the dialkylaniline-substituted alkynes and 7,7,8,8-tetracyanoquinodimethane (TCNQ) moieties. The resulting thin films showed potent redox activities and Ag ion sensing ability due to the formed CT chromophores.
通过二烷基苯胺取代的炔烃与7,7,8,8-四氰基对苯二醌二甲烷（TCNQ）部分之间高效的[2 + 2]环加成-逆电环化（CA-RE）反应，制备了具有明确电荷转移（CT）发色团的共价层层（LbL）薄膜。由于形成了CT发色团，所得薄膜表现出强大的氧化还原活性和银离子传感能力。
