Xu Xilian, Chen Ye, Liu Dongshu, Zheng Dong, Dai Xiaojing, Shi Wenhui, Cao Xiehong
College of Materials Science and Engineering, and Pinghu Institute of Advanced Materials, Zhejiang University of Technology, 18 Chaowang Road, Hangzhou, 310014, China.
Center for Membrane and Water Science & Technology, College of Chemical Engineering, Zhejiang University of Technology, 18 Chaowang Road, Hangzhou, 310014, China.
Chem Rec. 2022 Oct;22(10):e202200079. doi: 10.1002/tcr.202200079. Epub 2022 May 30.
Aqueous rechargeable zinc-ion batteries (ZIBs) featuring competitive performance, low cost and high safety hold great promise for applications in grid-scale energy storage and portable electronic devices. Metal-organic frameworks (MOFs), relying on their large framework structure and abundant active sites, have been identified as promising materials in ZIBs. This review comprehensively presents the current development of MOF-based materials including MOFs and their derivatives in ZIBs, which begins with Zn storage mechanism of MOFs, followed by introduction of various types of MOF-based cathode materials (PB and PBA, Mn-based MOF, V-based MOF, conductive MOF and their derivatives), and the regulation approaches for Zn deposition behavior. The key factors and optimization strategies of MOF-based materials that affect ZIBs performance are emphasized and discussed. Finally, the challenges and further research directions of MOF-based materials for advanced zinc-ion batteries are provided.
水系可充电锌离子电池（ZIBs）具有竞争力的性能、低成本和高安全性，在电网规模储能和便携式电子设备应用中具有广阔前景。金属有机框架材料（MOFs）凭借其大框架结构和丰富的活性位点，已被确认为锌离子电池中有前景的材料。本文综述全面介绍了基于MOF的材料（包括MOFs及其衍生物）在锌离子电池中的当前发展情况，首先介绍了MOFs的锌存储机制，接着介绍了各类基于MOF的正极材料（PB和PBA、锰基MOF、钒基MOF、导电MOF及其衍生物），以及锌沉积行为的调控方法。强调并讨论了影响锌离子电池性能的基于MOF的材料的关键因素和优化策略。最后，给出了用于先进锌离子电池的基于MOF的材料面临的挑战和进一步的研究方向。
