A new photoelectrochemical cell coupled with the Fenton reaction to remove pollutant and generate electricity under the drive of waste heat.

The water and energy crises are becoming increasingly serious with rapid population and economic development. It is urgent to develop new wastewater treatment technologies with high efficiency and low energy consumption. Herein, a solar-salinity nexus cell (called PRC) integrated by a photocatalytic fuel cell and reverse electrodialysis was combined with the Fenton reaction. The PRC-Fenton process can extract electrons from organic wastewater driven by salinity gradient energy for power generation and wastewater remediation in two chambers. The Fenton cathode MOF(2Fe/Co)-GO/GF with good electrocatalytic and photocatalytic activity was developed and optimized in a three-electrode system. GO doping obviously enhanced the catalytic activity and stability of the Fenton cathode. The pollutant (ampicillin, AMP) was simultaneously removed in both anode and cathode chambers of the PRC-Fenton system. AMP removal by the MOF(2Fe/Co)-GO/GF cathode remained above 95% in a wide range of pH values (3.0-7.0). The output current of the PRC-Fenton process was 1.7-2.4 mA. Compared to similar systems, PRC-Fenton is suitable for treating toxic and refractory organic pollutants with green energy in two chambers and generating electricity.