Key Laboratory of Biomass Chemical Engineering of the Ministry of Education, Institute of Industrial Ecology and Environment, College of Chemical and Biological Engineering, Zhejiang University (Yuquan Campus), Hangzhou 310027, China.
College of Environment, Zhejiang University of Technology, Hangzhou 310032, China.
J Environ Sci (China). 2022 Nov;121:25-37. doi: 10.1016/j.jes.2021.08.056. Epub 2022 Feb 1.
Volatile organic compound (VOC) emission control and source apportionment in small-scale industrial areas have become key topics of air pollution control in China. This study proposed a novel characteristic factor and pattern recognition (CF-PR) model for VOC source apportionment based on the similarity of characteristic factors between sources and receptors. A simulation was carried out in a typical industrial area with the CF-PR model involving simulated receptor samples. Refined and accurate source profiles were constructed through in situ sampling and analysis, covering rubber, chemicals, coating, electronics, plastics, printing, incubation and medical treatment industries. Characteristic factors of n-undecane, styrene, o-xylene and propane were identified. The source apportionment simulation results indicated that the predicted contribution rate was basically consistent with the real contribution rate. Compared to traditional receptor models, this method achieves notable advantages in terms of refinement and timeliness at similar accuracy, which is more suitable for VOC source identification and apportionment in small-scale industrial areas.
挥发性有机化合物(VOC)在小规模工业区域的排放控制和来源解析已成为中国空气污染控制的关键议题。本研究提出了一种基于源和受体之间特征因子相似性的新型特征因子和模式识别(CF-PR)模型,用于 VOC 源解析。使用 CF-PR 模型对典型工业区域的模拟受体样本进行了模拟。通过现场采样和分析构建了经过精炼和准确的源谱,涵盖了橡胶、化工、涂料、电子、塑料、印刷、孵化和医疗行业。鉴定出了十一烷、苯乙烯、邻二甲苯和丙烷的特征因子。源解析模拟结果表明,预测的贡献率与实际贡献率基本一致。与传统的受体模型相比,该方法在相似精度下具有显著的细化和及时性优势,更适用于小规模工业区域的 VOC 源识别和解析。