Synthesis and Characterization of A Stable Extra-Large-Pore Zeolite with 15×12×12 Member-Ring Channels.

Extra-large-pore zeolites have great application potential in various industrial fields, such as oil refinery, fine chemicals and biomass processing. Herein, we report the synthesis of an extra-large-pore germanosilicate zeolite (named NUD-13) by using an easily obtained aromatic organic cation 1,2-dimethyl-3-propyl-benzimidazolium as organic structure-directing agents. NUD-13 possesses a rare 15-member ring extra-large-pore channel intersecting with two elliptical 12-member ring channels, which is isostructural to germanosilicate zeolite GeZA synthesized by using triphenylsulfonium. The germanium in NUD-13 can be partially substituted by acid treatment to obtain stable high silica zeolite. In addition, aluminium is added into the framework of NUD-13 during the post-synthesis treatment process, which provides a foundation for catalytic application.