Chang William B, Evans Christopher M, Popere Bhooshan C, Russ Boris M, Liu Jun, Newman John, Segalman Rachel A
Departments of Chemical Engineering and Materials, University of California, Santa Barbara, California 93117, United States.
Department of Mechanical and Aerospace Engineering, North Carolina State University, Raleigh, North Carolina 27695, United States.
ACS Macro Lett. 2016 Jan 19;5(1):94-98. doi: 10.1021/acsmacrolett.5b00829. Epub 2015 Dec 24.
The Seebeck effect in unipolar ion-conducting, solid-state polymers is characterized. The high Seebeck coefficient and sign in polymer ion conductors is explained via analysis of thermogalvanic multicomponent transport. A solid-state, water-processeable, flexible device based on these materials is demonstrated, showcasing the promise of polymers as thermogalvanic materials. Thermogalvanic materials based on ion-conducting polymer membranes show great promise in the harvesting of waste heat.
对单极离子导电固态聚合物中的塞贝克效应进行了表征。通过对热电流多组分传输的分析，解释了聚合物离子导体中高塞贝克系数及其符号。展示了一种基于这些材料的固态、可水加工的柔性器件，突显了聚合物作为热电流材料的前景。基于离子导电聚合物膜的热电流材料在废热收集方面展现出巨大潜力。
