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新型查尔酮肟官能化氧化石墨烯作为盐酸溶液中碳钢缓蚀剂的性能评价

Performance Evaluation of New Chalcone Oxime Functionalized Graphene Oxide as a Corrosion Inhibitor for Carbon Steel in a Hydrochloric Acid Solution.

作者信息

Thoume Abderrahmane, Left Driss Benmessaoud, Elmakssoudi Abdelhakim, Achagar Redouane, Dakir Mohamed, Azzi Mohammed, Zertoubi Mustapha

机构信息

Laboratoire Interface Matériaux Environnement (LIME), Faculté des Sciences Ain Chock Université Hassan II de Casablanca, B.P 5366, Casablanca 20000, Morocco.

Laboratoire de Synthèse Organique, Extraction et Valorisation (LSOEV), Faculté des Sciences Ain Chock Université Hassan II de Casablanca, B.P 5366, Casablanca 20000, Morocco.

出版信息

Langmuir. 2022 Jun 21;38(24):7472-7483. doi: 10.1021/acs.langmuir.2c00441. Epub 2022 Jun 9.

Abstract

This study aims to synthesize new chalcone oxime functionalized graphene oxide (CO-GO) and investigate the enhancement in corrosion protection. The morphology and structure of the synthesized CO-GO have been characterized by elemental analysis: Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM). Moreover, the effectiveness of corrosion inhibition was investigated by utilizing electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP). The results of the above analyses demonstrate that CO-GO has an outstanding corrosion inhibitor performance of up to 94% and acts as a mixed-type inhibitor with a primarily anodic action. The effect of temperature on a carbon steel surface indicates that the tested composites are chemisorbed. A few techniques were able to provide surface characterization such as scanning electron microscopy and ultraviolet (UV)-visible spectroscopy to confirm inhibitor adsorption on the carbon steel surface.

摘要

本研究旨在合成新型查尔酮肟功能化氧化石墨烯(CO-GO)并研究其在腐蚀防护方面的增强效果。通过元素分析、傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)、热重分析(TGA)和扫描电子显微镜(SEM)对合成的CO-GO的形貌和结构进行了表征。此外,利用电化学阻抗谱(EIS)和动电位极化(PDP)研究了缓蚀效果。上述分析结果表明,CO-GO具有高达94%的优异缓蚀性能,并且作为一种主要具有阳极作用的混合型缓蚀剂。温度对碳钢表面的影响表明,测试的复合材料发生了化学吸附。一些技术能够提供表面表征,如扫描电子显微镜和紫外可见光谱,以确认缓蚀剂在碳钢表面的吸附。

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