A high-conductive, anti-freezing, antibacterial and anti-swelling starch-based physical hydrogel for multifunctional flexible wearable sensors.

Flexible wearable sensors based on conductive hydrogels are attracting increasing interest. To meet the urgent demands of sustainability and eco-friendliness, biopolymer-based physically crosslinked hydrogels have drawn great attention. Starch has a great potential due to its renewability, biocompatibility, nontoxicity and low cost. However, poor mechanical property, low conductivity and lack of versatility are seriously limiting the applications of starch-based hydrogels in wearable sensors. Moreover, the development of starch hydrogel-based wearable sensors in harsh conditions remains a challenge. Herein, multifunctional and physical crosslinking hydrogels were developed by introducing ionic liquid (1-ethyl-3-methyl imidazolium acetate) and metal salt (AlCl) into starch/polyvinyl alcohol double-network structure. The hydrogel exhibited excellent stretchability (567%), tensile strength (0.53 MPa), high conductivity (2.75 S·m), good anti-freezing, antibacterial and anti-swelling properties. A wearable sensor assembled from the starch-based hydrogel exhibited a wide working range, high sensitivity (gauge factor: 5.93) and excellent reversibility. Due to the versatility, the sensor effectively detected human motion in normal and underwater environment, and possessed a sensitive pressure and thermal response. Overall, the present work provided a promising route to develop multifunctional and "green" biopolymer-based hydrogels for wearable sensors in human health and sporting applications.