Marangoni Júnior Luís, Fozzatti Camila Rodrigues, Jamróz Ewelina, Vieira Roniérik Pioli, Alves Rosa Maria Vercelino
Packaging Technology Center, Institute of Food Technology, Av. Brasil, 2880, Campinas 13070-178, Brazil.
Department of Bioprocess and Materials Engineering, School of Chemical Engineering, University of Campinas, Campinas 13083-852, Brazil.
Materials (Basel). 2022 May 29;15(11):3881. doi: 10.3390/ma15113881.
Blend films based on sodium alginate (SA) and citrus pectin (P) reinforced with different concentrations of SiO (0-10% /) were developed in this study. From the morphological (SEM) and structural (FT-IR) evaluation, it was verified that the incorporation of the reinforcing agent did not drastically modify the microstructure of the films, nor did new chemical bonds form. However, the XRD results suggested a slight reduction in the crystallinities of the blends by the incorporation of SiO. Among the formulations prepared, the addition of a 5% reinforcing agent was responsible for the simultaneous improvement of mechanical and barrier properties. Comparing the control sample (SA/P) with the SA/P/5.0%SiO film, the tensile strength increased from 27.7 ± 3.7 to 40.6 ± 4.5 MPa, and the water-vapor transmission rate decreased from 319.8 ± 38.7 to 288.9 ± 23.5 g m day. Therefore, SiO as a reinforcing agent in SA/P blends, represents a simple and effective strategy for improving the properties of biopolymer-based films in applications, such as packaging.
本研究制备了基于海藻酸钠(SA)和柑橘果胶(P)并添加不同浓度SiO₂(0-10% /)增强的共混薄膜。通过形态学(扫描电子显微镜)和结构(傅里叶变换红外光谱)评估发现,增强剂的加入并未显著改变薄膜的微观结构,也未形成新的化学键。然而,X射线衍射结果表明,加入SiO₂后共混物的结晶度略有降低。在所制备的配方中,添加5%的增强剂可同时提高机械性能和阻隔性能。将对照样品(SA/P)与SA/P/5.0%SiO₂薄膜进行比较,拉伸强度从27.7±3.7MPa提高到40.6±4.5MPa,水蒸气透过率从319.8±38.7g m⁻² day⁻¹降低到288.9±23.5g m⁻² day⁻¹。因此,SiO₂作为SA/P共混物中的增强剂,是一种在包装等应用中改善生物聚合物基薄膜性能的简单有效策略。