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基于海藻酸钠和柑橘果胶并以二氧化硅增强的生物聚合物基薄膜。

Biopolymer-Based Films from Sodium Alginate and Citrus Pectin Reinforced with SiO.

作者信息

Marangoni Júnior Luís, Fozzatti Camila Rodrigues, Jamróz Ewelina, Vieira Roniérik Pioli, Alves Rosa Maria Vercelino

机构信息

Packaging Technology Center, Institute of Food Technology, Av. Brasil, 2880, Campinas 13070-178, Brazil.

Department of Bioprocess and Materials Engineering, School of Chemical Engineering, University of Campinas, Campinas 13083-852, Brazil.

出版信息

Materials (Basel). 2022 May 29;15(11):3881. doi: 10.3390/ma15113881.

Abstract

Blend films based on sodium alginate (SA) and citrus pectin (P) reinforced with different concentrations of SiO (0-10% /) were developed in this study. From the morphological (SEM) and structural (FT-IR) evaluation, it was verified that the incorporation of the reinforcing agent did not drastically modify the microstructure of the films, nor did new chemical bonds form. However, the XRD results suggested a slight reduction in the crystallinities of the blends by the incorporation of SiO. Among the formulations prepared, the addition of a 5% reinforcing agent was responsible for the simultaneous improvement of mechanical and barrier properties. Comparing the control sample (SA/P) with the SA/P/5.0%SiO film, the tensile strength increased from 27.7 ± 3.7 to 40.6 ± 4.5 MPa, and the water-vapor transmission rate decreased from 319.8 ± 38.7 to 288.9 ± 23.5 g m day. Therefore, SiO as a reinforcing agent in SA/P blends, represents a simple and effective strategy for improving the properties of biopolymer-based films in applications, such as packaging.

摘要

本研究制备了基于海藻酸钠(SA)和柑橘果胶(P)并添加不同浓度SiO₂(0-10% /)增强的共混薄膜。通过形态学(扫描电子显微镜)和结构(傅里叶变换红外光谱)评估发现,增强剂的加入并未显著改变薄膜的微观结构,也未形成新的化学键。然而,X射线衍射结果表明,加入SiO₂后共混物的结晶度略有降低。在所制备的配方中,添加5%的增强剂可同时提高机械性能和阻隔性能。将对照样品(SA/P)与SA/P/5.0%SiO₂薄膜进行比较,拉伸强度从27.7±3.7MPa提高到40.6±4.5MPa,水蒸气透过率从319.8±38.7g m⁻² day⁻¹降低到288.9±23.5g m⁻² day⁻¹。因此,SiO₂作为SA/P共混物中的增强剂,是一种在包装等应用中改善生物聚合物基薄膜性能的简单有效策略。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b0f3/9182168/24ec91681320/materials-15-03881-g001.jpg

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