在线热诱导气体分析：更新第 1 部分：EGA-MS。
On-Line Thermally Induced Evolved Gas Analysis: An Update-Part 1: EGA-MS.
机构信息
Department of Chemistry, "Sapienza" Università di Roma, P.le A.Moro 5, 00185 Rome, Italy.
出版信息
Molecules. 2022 May 30;27(11):3518. doi: 10.3390/molecules27113518.
Advances in on-line thermally induced evolved gas analysis (OLTI-EGA) have been systematically reported by our group to update their applications in several different fields and to provide useful starting references. The importance of an accurate interpretation of the thermally-induced reaction mechanism which involves the formation of gaseous species is necessary to obtain the characterization of the evolved products. In this review, applications of Evolved Gas Analysis (EGA) performed by on-line coupling heating devices to mass spectrometry (EGA-MS), are reported. Reported references clearly demonstrate that the characterization of the nature of volatile products released by a substance subjected to a controlled temperature program allows us to prove a supposed reaction or composition, either under isothermal or under heating conditions. Selected 2019, 2020, and 2021 references are collected and briefly described in this review.
本课题组系统地报道了在线热诱导气相分析（OLTI-EGA）的进展，以更新其在多个不同领域的应用，并提供有用的参考资料。为了获得对挥发产物的特征描述，有必要对涉及气态物质形成的热诱导反应机制进行准确的解释。在这篇综述中，报道了通过在线加热装置将热诱导气相分析（EGA）与质谱法（EGA-MS）联用的应用。所报道的参考文献清楚地表明，通过对受控温度程序释放的挥发性物质的特性进行表征，我们可以证明一种假设的反应或组成，无论是在等温条件下还是在加热条件下。本文综述了 2019、2020 和 2021 年的部分参考文献，并进行了简要描述。
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