Key Laboratory of Bio-Based Material Science and Technology, Ministry of Education, Northeast Forestry University, 26 Hexing Road, Harbin 150040, China.
School of Architecture, University of Nevada-Las Vegas, 4505 S. Maryland Pkwy, Las Vegas, NV 89154, USA.
Molecules. 2022 Jun 5;27(11):3626. doi: 10.3390/molecules27113626.
Very volatile organic compounds (VVOCs) are a group of important odor pollutants affecting indoor air quality that have been shown to be harmful to human health. A 15 L environmental chamber, combined with multi-bed tube was used to collect gases. Fifteen very volatile organic compounds (VVOCs), including 12 odor compounds, were identified from veneered medium density fiberboard coated with water-based lacquer (WB-MDF) using gas chromatography-mass spectrometry/olfactometry (GC-MS/O). The total very volatile organic compound (TVVOC) and total odor intensity (TOI) showed a decreasing trend over time, reaching equilibrium on day 28. TVVOC showed an overall slow-fast-slow emission profile, from day 3 to day 7, with a maximum decay rate of 29.7%. TOI showed the greatest rate of decline from day 1 to day 3, at approximately 12%. Alkane and alcohol VVOCs were the more abundant compounds, accounting for at least 60% and even up to 80% of the total. The major odor impression was fruity, with a highest odor rating of 6.6, followed by sweet, with an odor rating of 6.1. Although the odor impression changed from sweet to fruity over time, it seemed pleasant overall. The odor contributors were mainly alkanes, alcohols, esters, and ethers, which had relatively high odor intensities. The main odor-contributing substances were dichloromethane, ethanol, ethyl acetate, 2-methylacrylic acid methyl ester, and tetrahydrofuran. When WB-MDF is used for furniture or other decorative materials, it is strongly recommended that it be stored under ventilation for at least 28 days and the adoption of substitute solvents of lacquers, modified adhesives, and low-odor wood raw materials is recommended. These possible initiatives would contribute to the aim of building an environmentally friendly indoor environment.
非常挥发性有机化合物 (VVOCs) 是一组影响室内空气质量的重要气味污染物,已被证明对人类健康有害。使用 15 L 环境室和多床管收集气体。使用气相色谱-质谱/嗅闻法 (GC-MS/O) 从涂有水基清漆的贴面板中鉴定出 15 种非常挥发性有机化合物 (VVOCs),包括 12 种气味化合物。涂有水基清漆的中密度纤维板 (WB-MDF) 中的总非常挥发性有机化合物 (TVVOC) 和总气味强度 (TOI) 随时间呈下降趋势,在第 28 天达到平衡。TVVOC 显示出从第 3 天到第 7 天的整体慢-快-慢释放曲线,最大衰减率为 29.7%。TOI 显示从第 1 天到第 3 天下降最快,约为 12%。烷烃和醇类 VVOC 是含量较高的化合物,至少占 60%,甚至高达 80%。主要气味印象是水果味,气味评分为 6.6,其次是甜味,气味评分为 6.1。尽管随着时间的推移,气味印象从甜味变为水果味,但总体上似乎令人愉悦。气味贡献者主要是烷烃、醇类、酯类和醚类,它们具有相对较高的气味强度。主要的气味贡献物质是二氯甲烷、乙醇、乙酸乙酯、2-甲基丙烯酸甲酯和四氢呋喃。当 WB-MDF 用于家具或其他装饰材料时,强烈建议将其在通风条件下储存至少 28 天,并建议采用替代溶剂清漆、改良胶黏剂和低气味木材原料。这些可能的举措将有助于实现建立环保室内环境的目标。