Synthesis, characterization and photo-catalytic activity of guar-gum--aliginate@silver bionanocomposite material.

The green mechanism for the synthesis of nanoparticles and their application to the wastewater treatment is of inordinate curiosity to the research community. Herein we outline a novel method for the synthesis of silver nanoparticles a green route using alginate-guar gum blend (GG-Alg@Ag) and their application to degrade methylene blue (MB) dye. The synthesized material was characterized by FTIR, XRD, SEM-EDX, TEM, TGA-DTG, AFM, and UV-vis techniques. A combination of RSM and CCD was employed to compute the system and optimized values of various interacting parameters such as exposure time (120 min), pH (4.98), dye concentration (194 mg L), and catalyst dose (0.07 g) with a photodegradation capacity of 92.33% and desirability 1.0. The mechanism of degradation reaction was best elucidated by the pseudo-second-order model suggesting chemical deposition of MB on the GG-Alg@Ag surface through followed by the reduction mechanism in the occupancy of visible light. The optical studies indicated a value of 2.5 eV by Tauc's plot for bandgap energy ( ) for GG-Alg@Ag bionanocomposite.