Suppr超能文献

[运城市夏季大气挥发性有机化合物污染特征及来源解析]

[Pollution Characteristics and Source Apportionment of Atmospheric Volatile Organic Compounds in Summer in Yuncheng City].

作者信息

Wen Xiao-Yu, Zhao Wen-Ting, Luo Shu-Zhen, Zhang Qiang, Wang Yun-Tao, Ma Jun-Jie, Liu Xin-Gang

机构信息

College of Urban and Environmental Science, Northwestern University, Xi'an 710127, China.

School of Environment, Beijing Normal University, Beijing 100875, China.

出版信息

Huan Jing Ke Xue. 2022 Jun 8;43(6):2979-2986. doi: 10.13227/j.hjkx.202109134.

Abstract

Based on the online monitoring data of VOCs, O, and NO in Yuncheng City from June to August 2020, the pollution characteristics of VOCs in Yuncheng City in summer were analyzed. At the same time, the main emission sources were determined using a PMF model, and the chemical reactivity of VOCs was evaluated using the maximum incremental reactivity (MIR) method and fractional aerosol coefficients (FAC). The results showed that the urban area of Yuncheng was seriously polluted by VOCs and NO in the early morning and evening during summer, the peak value of VOCs daily variation occurred at 08:00 and 20:00, respectively, and was mainly affected by the morning and evening peaks in traffic. The (VOCs) from June to August was 50.52 μg·m, and the species with the highest proportion were alkanes (39.39%) and oxygenated volatile organic compounds (OVOCs, 34.63%). Five VOCs emission sources were determined by the PMF model, of which the largest contribution was from motor vehicle exhaust emission sources (33.10%), followed by industrial emission sources (29.46%), natural gas and coal combustion sources (17.31%), solvent use sources (11.94%), and plant emission sources (8.19%). Controlling motor vehicle exhaust emission sources is the key to alleviate VOCs pollution in summer in Yuncheng City. The average ozone formation potential (OFP) of VOCs was 162.88 μg·m, in which OVOCs had the highest contribution rate (45.37%); acetaldehyde, propionaldehyde, ethylene, isoprene, and toluene were the key active components; and industrial emission sources were the emission sources with the highest contribution rate. The average value of secondary organic aerosol formation potential (SOA) of VOCs was 0.40 μg·m, in which the contribution rate of aromatic hydrocarbons was the highest (88.00%), and the solvent use source was the emission source with the highest contribution rate.

摘要

基于2020年6月至8月运城市挥发性有机物(VOCs)、臭氧(O₃)和氮氧化物(NO)的在线监测数据,分析了运城市夏季VOCs的污染特征。同时,利用正定矩阵因子分解(PMF)模型确定主要排放源,并采用最大增量反应活性(MIR)方法和分数气溶胶系数(FAC)评估VOCs的化学反应活性。结果表明,运城市区夏季早晚时段VOCs和NO污染严重,VOCs日变化峰值分别出现在08:00和20:00,主要受早晚交通高峰影响。6月至8月VOCs平均质量浓度为50.52 μg·m⁻³,占比最高的物种为烷烃(39.39%)和含氧挥发性有机化合物(OVOCs,34.63%)。通过PMF模型确定了5个VOCs排放源,其中机动车尾气排放源贡献最大(33.10%),其次是工业排放源(29.46%)、天然气和煤炭燃烧源(17.31%)、溶剂使用源(11.94%)和植物排放源(8.19%)。控制机动车尾气排放源是缓解运城市夏季VOCs污染的关键。VOCs的平均臭氧生成潜势(OFP)为162.88 μg·m⁻³,其中OVOCs贡献率最高(45.37%);乙醛、丙醛、乙烯、异戊二烯和甲苯是关键活性组分;工业排放源是贡献率最高的排放源。VOCs的二次有机气溶胶生成潜势(SOA)平均值为0.40 μg·m⁻³,其中芳香烃贡献率最高(88.00%),溶剂使用源是贡献率最高的排放源。

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验