Li Gui-Fang, Yang Heng, Ye Yuan-Hang, Chen Qing-Fei, Cui Rong-Yang, Chen An-Qiang, Zhang Dan
College of Resources and Environment, Yunnan Agricultural University, Kunming 650201, China.
Key Laboratory of Mountain Surface Processes and Ecological Regulation, Chinese Academy of Sciences, Institute of Mountain Hazards and Environment, Chinese Academy of Sciences and Ministry of Water Resources, Chengdu 610041, China.
Huan Jing Ke Xue. 2022 Jun 8;43(6):3027-3036. doi: 10.13227/j.hjkx.202109195.
Shallow groundwater around plateau lakes is one of the important sources of production and potable water. Shallow groundwater NO-N pollution driven by factors such as surface nitrogen input load, rainfall, and irrigation is serious and threatens the water quality of plateau lakes. In order to identify the characteristics of nitrogen pollution and its driving factors in shallow groundwater, 463 shallow groundwater samples were collected from wells in farmland and residential areas around eight plateau lakes of Yunnan in the rainy and dry seasons in 2020 and 2021. The results showed that the average values of (TN), (NO-N), (ON), and (NH-N) in shallow groundwater were 24.35, 15.15, 8.41, and 0.79 mg·L, respectively. Nearly 32% of the shallow groundwater samples around the eight lakes failed to meet the groundwater Class Ⅲ water quality requirements (GB/T 14848) of 20 mg·L for NO-N. Among them, the NO-N concentration in the shallow groundwater around Erhai Lake, Qiluhu Lake, and Dianchi Lake had the highest rate of exceeding the standard, followed by that around Xingyunhu Lake, Yangzonghai Lake, Yilonghu Lake, Fuxianhu Lake, and Chenghai Lake as the smallest. Land use and seasonal changes affected the concentration and composition of various forms of nitrogen in shallow groundwater. The concentration of various forms of nitrogen in shallow groundwater in the farmland area was higher than that in the residential area. The nitrogen concentration in shallow groundwater in farmland was higher than that in residential areas. Except for NH-N, the concentration of various forms of nitrogen in shallow groundwater in the rainy season was higher than that in the dry season. NO-N was the main nitrogen form in shallow groundwater; the fraction of TN was 57%-68%, and the fraction of ON was 27%-38%. The EC, DO, ORP, and in shallow groundwater were the key factors reflecting or affecting the concentration of various forms of nitrogen in shallow groundwater, whereas soil factors had a weak impact on the concentration of various forms of nitrogen in shallow groundwater.
高原湖泊周边的浅层地下水是生产和饮用水的重要水源之一。受地表氮输入负荷、降雨和灌溉等因素驱动,浅层地下水的NO-N污染严重,威胁着高原湖泊的水质。为了识别浅层地下水中氮污染特征及其驱动因素,于2020年和2021年的雨季和旱季,从云南8个高原湖泊周边农田和居民区的水井中采集了463个浅层地下水样本。结果表明,浅层地下水中(TN)、(NO-N)、(ON)和(NH-N)的平均值分别为24.35、15.15、8.41和0.79mg·L。8个湖泊周边近32%的浅层地下水样本不符合GB/T 14848规定的20mg·L的地下水Ⅲ类水质标准。其中,洱海、杞麓湖和滇池周边浅层地下水中NO-N浓度超标率最高,星云湖、阳宗海、异龙湖、抚仙湖和程海周边次之。土地利用和季节变化影响了浅层地下水中各种形态氮的浓度和组成。农田区浅层地下水中各种形态氮的浓度高于居民区。除NH-N外,雨季浅层地下水中各种形态氮的浓度高于旱季。NO-N是浅层地下水中的主要氮形态;TN的占比为57%-68%,ON的占比为27%-38%。浅层地下水的EC、DO、ORP和是反映或影响浅层地下水中各种形态氮浓度的关键因素,而土壤因素对浅层地下水中各种形态氮浓度的影响较弱。