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[长江三角洲一体化示范区青浦区表层沉积物中有机质的分布特征、来源分析及污染评价]

[Distribution Characteristics, Source Analysis, and Pollution Evaluation of Organic Matter in Surface Sediments of Qingpu District, Yangtze River Delta Integration Demonstration Area].

作者信息

Zhang Zhi-Bo, Duan Yan-Ping, Tu Yao-Jen, Luo Peng-Cheng, Gao Jun

机构信息

School of Environmental Geographical Sciences, Shanghai Normal University, Shanghai 200234, China.

Yangtze River Delta Urban Wetland Ecosystem National Field Observation and Research Station, Shanghai 200234, China.

出版信息

Huan Jing Ke Xue. 2022 Jun 8;43(6):3066-3076. doi: 10.13227/j.hjkx.202107175.

Abstract

The surface sediments were collected from 25 sampling points in the Qingpu District of the Yangtze River Delta integration demonstration area, and the total organic carbon (TOC), total nitrogen (TN), organic carbon isotope (C), and nitrogen isotope (N) content in the samples were analyzed. The distribution characteristics and potential sources of organic matter in the surface sediments were discussed in detail, and the organic pollution index was also evaluated. The results showed that the (TOC) in the surface sediments of 31 sampling points in Qingpu District was 0.21%-3.55%, with an average value of 1.18%; (TN) ranged from 0.02% to 0.23%, with an average value of 0.09%. The C ranged from -28.04‰ to -10.80 ‰, with an average of -22.28‰, and the N ranged from 2.28‰ to 11.19‰, with an average of 5.76‰. The TOC content was significantly correlated with the TN content. Source analysis showed that the organic matter in the surface sediments of the study area was mainly affected by soil organic matter, sewage organic matter, and terrestrial plants. The calculation results of the contribution rate based on IsoSource software showed that the relative contribution rate of soil organic matter was relatively high (0.3%-96.8%), and domestic sewage had a certain contribution to the organic matter source of most sampling points. In addition, the selected end-member substances had certain differences in the contribution of organic matter sources in samples of different land use types. The evaluation index of organic pollution in the surface sediments of the study area ranged from 0.006-0.745, with an average value of 0.163, indicating that the organic pollution of the study area was considered lightly polluted. Among them, the pollution of sampling points around the Jinze Reservoir was more serious than that in other areas, indicating that there was a potential risk of eutrophication in this area, which requires certain attention.

摘要

在长江三角洲一体化示范区青浦区的25个采样点采集表层沉积物,分析样品中的总有机碳(TOC)、总氮(TN)、有机碳同位素(δ¹³C)和氮同位素(δ¹⁵N)含量。详细讨论了表层沉积物中有机质的分布特征和潜在来源,并对有机污染指数进行了评价。结果表明,青浦区31个采样点表层沉积物中TOC为0.21% - 3.55%,平均值为1.18%;TN为0.02% - 0.23%,平均值为0.09%。δ¹³C为 - 28.04‰至 - 10.80‰,平均为 - 22.28‰,δ¹⁵N为2.28‰至11.19‰,平均为5.76‰。TOC含量与TN含量显著相关。源分析表明,研究区表层沉积物中的有机质主要受土壤有机质、污水有机质和陆生植物的影响。基于IsoSource软件的贡献率计算结果表明,土壤有机质的相对贡献率较高(0.3% - 96.8%),生活污水对大多数采样点的有机质来源有一定贡献。此外,所选端元物质在不同土地利用类型样品的有机质来源贡献上存在一定差异。研究区表层沉积物有机污染评价指数为0.006 - 0.745,平均值为0.163,表明研究区有机污染为轻度污染。其中,金泽水库周边采样点的污染比其他区域更严重,表明该区域存在富营养化潜在风险,需予以一定关注。

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