Ikeshita Masahiro, Mizugaki Momo, Ishikawa Takahiro, Matsudaira Kana, Kitahara Maho, Imai Yoshitane, Tsuno Takashi
Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, Narashino, Chiba 275-8575, Japan.
Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan.
Chem Commun (Camb). 2022 Jul 5;58(54):7503-7506. doi: 10.1039/d2cc01959k.
The handedness of circularly polarized luminescence (CPL) of Zn(II) complexes with a chiral Schiff-base ligand can be controlled by coordination geometry changes in solution and in the solid state. The relationships between molecular structure and chiroptical properties were discussed with the results of X-ray diffraction analysis and DFT calculations.