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Sign control of circularly polarized luminescence of chiral Schiff-base Zn(II) complexes through coordination geometry changes.

作者信息

Ikeshita Masahiro, Mizugaki Momo, Ishikawa Takahiro, Matsudaira Kana, Kitahara Maho, Imai Yoshitane, Tsuno Takashi

机构信息

Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, Narashino, Chiba 275-8575, Japan.

Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan.

出版信息

Chem Commun (Camb). 2022 Jul 5;58(54):7503-7506. doi: 10.1039/d2cc01959k.

DOI:10.1039/d2cc01959k
PMID:35698874
Abstract

The handedness of circularly polarized luminescence (CPL) of Zn(II) complexes with a chiral Schiff-base ligand can be controlled by coordination geometry changes in solution and in the solid state. The relationships between molecular structure and chiroptical properties were discussed with the results of X-ray diffraction analysis and DFT calculations.

摘要

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