Attachment and detachment of large microplastics in saturated porous media and its influencing factors.

Groundwater contamination by microplastics (MPs) has been gradually regarded as a potential human health risk, which calls for detailed investigation of MPs transport behavior in saturated zone. In this study, a series of sand column experiments were carried out to investigate the transport characteristics of large MPs with its diameter of 10-20 μm in porous media, in which the effects of different hydrological conditions and MPs characteristics were examined. Experimental results showed that the increase of water flow rate from 2.2 to 7.5 mL/min significantly increased the maximal outlet MPs concentration by two orders of magnitude, while a larger ratio of MPs diameter to soil particle diameter decreased its mobility. The increase of water salinity from 0 to 25 mmol/L (NaCl) decreased the maximal outlet MPs concentration by 50.5-68.4% for different sized MPs. Since chemical aging would lead to the formation of oxygen-containing functional groups and make MPs more negatively charged, it greatly increased the maximal outlet MPs concentration by 0.53-5.67 times. Compared with the traditional attachment model (AM), the attachment-detachment model (ADM) could better simulate the gradual desorption of large MPs from soil in the process of clean water flushing, indicating the nonnegligible detachment of large MPs from soil. In ADM, the desorption coefficient gradually decreased in the process of clean water flushing, which was only 31.6% of the initial value after flushing kept for 10 PV. Moreover, the equations to calculate the adsorption and desorption coefficients of MPs in the saturated zone were developed, which considered both MPs and aquifer characteristics. Results from this study described the desorption of large MPs in porous media under various conditions, which expands our knowledge about the fate and risk of MPs in underground environment.