A High-Nuclear Isopolymolybdate Cluster Assembled with an Anionic [{Mo O (OMe) }] and Two Charge-Neutral [{Mo O (OMe) }] Cages.
作者信息
Wang Yingyue, Ma Xinyi, Li Guoao, Li Huafeng, Wang Quanzhong, Chen Wenjing, Ma Pengtao, Li Shuhua, Niu Jingyang, Wang Jingping
机构信息
Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004, P. R. China.
Key Laboratory of Mesoscopic Chemistry of Ministry of Education, Institute of Theoretical and Computational Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P. R. China.
出版信息
Chemistry. 2022 Sep 22;28(53):e202200637. doi: 10.1002/chem.202200637. Epub 2022 Aug 1.
We synthesized a high-nuclear isopolymolybdate cluster (n-Bu N) H [{Mo O (OMe) }{Mo O (OMe) } ] ⋅ 25H O ⋅ 6CH CN (1) by using [Mo O ] as the base precursor. Crystallographic characterization shows the cluster is composed of an anionic [{Mo O (OMe) }] cage and two charge-neutral [{Mo O (OMe) }] cages. Supported by the electrospray ionization mass spectrometry study, the polyoxoanion structural unit [Mo O (CH O) ] demonstrates strong stability in acetonitrile solution. Moreover, 1 exhibits good proton conductivity of 1.79×10 S cm at 358 K and 98 % relative humidity.
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