Li Hai-Yang, Hua Xue, Fu Ting, Liu Xiao-Fei, Zang Shuang-Quan
Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China.
Chem Commun (Camb). 2022 Jul 12;58(56):7753-7756. doi: 10.1039/d2cc02703h.
A pair of novel multifunctional MOF materials [Cd(L)(D/L-Lm)(HO)]·5HO (denoted as D/L-Cd-MOF) has been synthesized by combining the viologen-functionalized ligand HLCl and chiral D/L-tartaric acid (HLm) with a simple solvothermal method. Due to the unique photoelectric response properties of the viologen units, reversible photochromic and electrochromic properties have been combined in D/L-Cd-MOF, which points to a new way of designing and constructing multifunctional photoelectric materials.
通过将紫精功能化配体HLCl和手性D/L-酒石酸（HLm）与简单的溶剂热法相结合，合成了一对新型多功能金属有机框架材料[Cd(L)(D/L-Lm)(HO)]·5HO（表示为D/L-Cd-MOF）。由于紫精单元独特的光电响应特性，D/L-Cd-MOF兼具可逆光致变色和电致变色特性，这为设计和构建多功能光电材料指明了一条新途径。
