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用于高面积能量密度固态超级电容器应用的高孔隙率多孔碳

Highly Porous Holey Carbon for High Areal Energy Density Solid-State Supercapacitor Application.

作者信息

Young Christine, Chen Hong-Ting, Guo Sahn-Ze

机构信息

Functional Nanoporous Materials Laboratory, Department of Chemical and Materials Engineering, National Yunlin University of Science and Technology, Yunlin 640, Taiwan.

出版信息

Micromachines (Basel). 2022 Jun 9;13(6):916. doi: 10.3390/mi13060916.

DOI:10.3390/mi13060916
PMID:35744530
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9229398/
Abstract

Biomass materials are perceived as sustainable, carbon-rich precursors for the fabrication of carbon materials. In this study, we demonstrated the capacitance performance of biomass-derived carbon, produced by using golden shower tree seeds (GTs) as carbon precursors and potassium ferrate (KFeO) as the activation agent. The as-prepared porous carbon (GTPC) possessed an ultrahigh specific surface area (1915 m g) and abundant pores. They also exhibited superior electrochemical performance, owing to their well-constructed porous structure, high surface area, and optimized porous structure. Optimized activated carbon (GTPC-1) was used to assemble a symmetric solid-state supercapacitor device with poly(vinyl alcohol) (PVA)/HSO as a solid-state gel electrolyte. The device exhibited a maximum areal energy density of 42.93 µWh cm at a power density of 520 µW cm.

摘要

生物质材料被视为用于制造碳材料的可持续、富含碳的前驱体。在本研究中,我们展示了以黄金雨树种子(GTs)为碳前驱体、高铁酸钾(KFeO)为活化剂制备的生物质衍生碳的电容性能。所制备的多孔碳(GTPC)具有超高的比表面积(1915 m²/g)和丰富的孔隙。由于其结构良好的多孔结构、高比表面积和优化的孔隙结构,它们还表现出优异的电化学性能。优化后的活性炭(GTPC-1)用于组装以聚(乙烯醇)(PVA)/HSO为固态凝胶电解质的对称固态超级电容器器件。该器件在功率密度为520 μW/cm²时表现出最大面积能量密度为42.93 μWh/cm²。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/881cc760b9e0/micromachines-13-00916-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/85f93f0da1cc/micromachines-13-00916-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/53d8bbb5eb6f/micromachines-13-00916-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/eb6762abe300/micromachines-13-00916-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/a904fc0b3ecf/micromachines-13-00916-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/bdc5db3dd2f2/micromachines-13-00916-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/2f14bc18da5c/micromachines-13-00916-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/881cc760b9e0/micromachines-13-00916-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/85f93f0da1cc/micromachines-13-00916-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/53d8bbb5eb6f/micromachines-13-00916-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/eb6762abe300/micromachines-13-00916-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/a904fc0b3ecf/micromachines-13-00916-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/bdc5db3dd2f2/micromachines-13-00916-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/2f14bc18da5c/micromachines-13-00916-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0f5/9229398/881cc760b9e0/micromachines-13-00916-g006.jpg

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