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非铜涂层实心焊丝中添加改性C-WS-(FeO + TiN)纳米添加剂润滑的钢/铜摩擦副的高温摩擦学性能

High Temperature Tribological Performance of Steel/Copper Friction Pairs Lubricated with a Modified C-WS-(FeO + TiN) Nanoadditives in Non-Copper Coated Solid Wires.

作者信息

Li Hong, Zhu Jing, Chen Zisong, Li Zhuoxin, Meng Bo

机构信息

Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, China.

Shandong Juli Welding Co., Ltd., Dezhou 253011, China.

出版信息

Nanomaterials (Basel). 2022 Jun 17;12(12):2091. doi: 10.3390/nano12122091.

Abstract

In this study, four kinds of nanoparticles, graphite, WS, FeO, and TiN, were used as lubricating additives for steel/copper friction pairs to solve the problem of welding contact tube wear with non-copper-coated solid wire at high temperature. The single and composite nanoparticles have excellent dispersion stability in absolute ethanol under the action of the compound surfactant NaSTA + OA + PVP (i.e., sodium stearate, oleic acid, and polyvinylpyrrolidone). The tribological test results showed that the maximum decrement, with reference to the average coefficient of friction and wear volumes, were measured with nanoparticle concentration in 1:1:1 ratio at 300 °C. Compared with dry friction, the average friction coefficient and wear volume are reduced by 74.3% and 84.8%, respectively, which may be attributed to the formation of a stable tribo-film mainly composed of C-O, FeO, WO, TiO, TiNO composite on the worn surface. Therefore, it is considered that the combined lubrication effects of the ball-bearing effect, repairing of worn surfaces, and the tribo-film resulted in the lowest friction and wear.

摘要

在本研究中,使用了四种纳米颗粒,即石墨、WS、FeO和TiN,作为钢/铜摩擦副的润滑添加剂,以解决高温下无铜包层实心焊丝焊接接触管磨损的问题。在复合表面活性剂NaSTA + OA + PVP(即硬脂酸钠、油酸和聚乙烯吡咯烷酮)的作用下,单一和复合纳米颗粒在无水乙醇中具有优异的分散稳定性。摩擦学测试结果表明,在300℃下,纳米颗粒浓度为1:1:1时,相对于平均摩擦系数和磨损体积,降幅最大。与干摩擦相比,平均摩擦系数和磨损体积分别降低了74.3%和84.8%,这可能归因于在磨损表面形成了主要由C-O、FeO、WO、TiO、TiNO复合材料组成的稳定摩擦膜。因此,认为滚珠轴承效应、磨损表面修复和摩擦膜的综合润滑作用导致了最低的摩擦和磨损。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5270/9229732/dca75b9cac23/nanomaterials-12-02091-g001.jpg

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