Wang Sijiao, Chen Mengmeng, Cao Kaiming
Department of Mechatronic Engineering, School of Mechanical and Electrical Engineering, Xi'an Technological University, Xi'an 710021, China.
Department of Polymer Science and Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China.
Polymers (Basel). 2022 Jun 12;14(12):2374. doi: 10.3390/polym14122374.
Thermoplastic polyolefins, such as polyethylene (PE), are traditionally one of the most widely used polymer classes with applications in the electric industry, and their nanocomposites have caught the interest of researchers. The linear filler is shown to be beneficial in decreasing the charge injection and hindering the formation of charge packs. So, we demonstrate a novel composite with excellent properties. The low-density polyethylene (LDPE) composite with aligned aluminum oxide (AlO) fiber has been prepared in electric field conditions. The direction of the AlO fiber was parallel to the thickness direction of the LDPE composite. The breakdown strength of the AlO/LDPE composite with 0.2% aligned AlO fiber was 498 kV/mm, which is higher than other fillers induced. The aligned AlO fiber has effect on preventing accumulation of space charge and reducing the amount of free electron in the material. In addition, the thermal conductivity of the LDPE composite (0.22 W/m·K) was increased to 0.85 W/m·K when doped with 0.5 wt% aligned AlO fiber. The present structure provides a new possibility for mass new nanocomposites with excellent microstructures and remarkable functionality.
热塑性聚烯烃,如聚乙烯(PE),传统上是应用于电气工业的最广泛使用的聚合物类别之一,其纳米复合材料引起了研究人员的兴趣。线性填料被证明有利于减少电荷注入并阻碍电荷包的形成。因此,我们展示了一种具有优异性能的新型复合材料。在电场条件下制备了具有取向氧化铝(AlO)纤维的低密度聚乙烯(LDPE)复合材料。AlO纤维的方向与LDPE复合材料的厚度方向平行。含有0.2%取向AlO纤维的AlO/LDPE复合材料的击穿强度为498 kV/mm,高于其他填料诱导的击穿强度。取向AlO纤维对防止空间电荷积累和减少材料中的自由电子数量有作用。此外,当掺杂0.5 wt%取向AlO纤维时,LDPE复合材料的热导率(0.22 W/m·K)提高到了0.85 W/m·K。目前的结构为具有优异微观结构和显著功能的大量新型纳米复合材料提供了新的可能性。