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中国泉州湾沉积物中潜在有毒元素的多元统计分析:空间关系、生态毒性和来源识别。

Multivariate statistical analysis of potentially toxic elements in the sediments of Quanzhou Bay, China: Spatial relationships, ecological toxicity and sources identification.

机构信息

Key Laboratory of Global Change and Marine Atmospheric Chemistry, Third Institute of Oceanography, Ministry of Natural Resources, Xiamen, 361005, China.

Key Laboratory of Global Change and Marine Atmospheric Chemistry, Third Institute of Oceanography, Ministry of Natural Resources, Xiamen, 361005, China.

出版信息

Environ Res. 2022 Oct;213:113750. doi: 10.1016/j.envres.2022.113750. Epub 2022 Jun 23.

Abstract

In this paper, the spatial distribution, pollution degree, ecological toxicity and possible sources of seven potentially toxic elements (PTEs) collected from the surface sediments of Quanzhou Bay (QZB) were analyzed by obtaining concentration measurements. The results indicated that the areas with high Cu, Pb, Zn and Hg concentrations were mainly located in the Luoyang River estuary, while the areas with high contents of Cd and As appeared in the Luoyang River estuary area and in the southern part of QZB, respectively. The contamination indices showed that the Cd pollution degree was slight to serious, while other elements were slightly enriched. The calculation results of the potential ecological risk index (RI) and toxic risk index (TRI) indicated that Cd was the main element posing ecological risk among the PTEs of sediments in QZB, followed by Hg. Moreover, in approximately 30% of the surveyed sites, PTEs exhibited low toxicity to aquatic ecosystems. Finally, the self-organizing map (SOM) and positive matrix factorization (PMF) model were used to determine the PTEs sources. Natural sources, industrial emissions, and the combustion of fossil fuels were three main sources for PTEs in the surface sediments of QZB. This study provides a reference for assessing sediment pollution and managing marine pollution in QZB.

摘要

本文通过获取浓度测量值,分析了泉州湾(QZB)表层沉积物中采集的七种潜在有毒元素(PTEs)的空间分布、污染程度、生态毒性和可能来源。结果表明,Cu、Pb、Zn 和 Hg 浓度较高的区域主要位于洛阳河口,而 Cd 和 As 含量较高的区域分别出现在洛阳河口区和 QZB 南部。污染指数表明,Cd 的污染程度为轻微到严重,而其他元素则略有富集。潜在生态风险指数(RI)和毒性风险指数(TRI)的计算结果表明,Cd 是 QZB 沉积物中 PTEs 生态风险的主要元素,其次是 Hg。此外,在大约 30%的调查点,PTEs 对水生生态系统表现出低毒性。最后,采用自组织映射(SOM)和正矩阵因子分解(PMF)模型确定了 PTEs 的来源。自然源、工业排放和化石燃料燃烧是泉州湾表层沉积物中 PTEs 的三个主要来源。本研究为评估 QZB 沉积物污染和管理海洋污染提供了参考。

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