Ren Ling, Liu Qi, Ni Yang, Xia Yucong, Chen Jianguo
Department of Thermal Science and Energy Engineering, University of Science and Technology Beijing, No. 30 Xueyuan Road, Haidian District, Beijing 100083, China.
Department of Engineering Physics, Tsinghua University, No. 1 Qinghua Yuan, Haidian District, Beijing 100084, China.
ACS Omega. 2022 Jun 9;7(24):20833-20844. doi: 10.1021/acsomega.2c01436. eCollection 2022 Jun 21.
To improve the efficiency of CO geological sequestration, it is of great significance to in-depth study the physical mechanism of the immiscible CO-water displacement process, where the influential factors can be divided into fluid-fluid and fluid-solid interactions and porous media characteristics. Based on the previous studies of the interfacial tension (capillary number) and viscosity ratio factors, we conduct a thorough study about the effects of fluid-solid interaction (i.e., wettability) and porous media characteristics (i.e., porosity and non-uniformity of granule size) on the two-phase displacement process by constructing porous media with various structural parameters and using a multiphase lattice Boltzmann method. The displacement efficiency of CO is evaluated by the breakthrough time characterizing the displacement speed and the quasi-steady state saturation representing the displacement amount. It is shown that the breakthrough time of CO becomes longer, but the quasi-steady state saturation increases markedly with the increase in CO wettability with the surface, demonstrating an overall improvement of the displacement efficiency. Furthermore, the breakthrough time of CO shortens and the saturation increases significantly with increasing porosity, granule size, and non-uniformity, showing the improvement of the displacement efficiency. Therefore, enhancing the wettability of CO with the surface and selecting reservoirs with greater porosity, larger granule size, and non-uniformity can all contribute to the efficiency improvement of CO geological sequestration.
为提高二氧化碳地质封存效率,深入研究二氧化碳与水不混溶驱替过程的物理机制具有重要意义,其中影响因素可分为流体-流体和流体-固体相互作用以及多孔介质特性。基于先前对界面张力(毛细管数)和粘度比因素的研究,我们通过构建具有不同结构参数的多孔介质并使用多相格子玻尔兹曼方法,深入研究了流体-固体相互作用(即润湿性)和多孔介质特性(即孔隙率和颗粒尺寸不均匀性)对两相驱替过程的影响。通过表征驱替速度的突破时间和代表驱替量的准稳态饱和度来评估二氧化碳的驱替效率。结果表明,随着二氧化碳与表面润湿性的增加,二氧化碳的突破时间变长,但准稳态饱和度显著增加,表明驱替效率总体提高。此外,随着孔隙率、颗粒尺寸和不均匀性的增加,二氧化碳的突破时间缩短且饱和度显著增加,表明驱替效率提高。因此,增强二氧化碳与表面的润湿性以及选择孔隙率更大、颗粒尺寸更大和不均匀性更大的储层都有助于提高二氧化碳地质封存效率。