• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

通过酰亚胺/亚胺有机笼分离一氧化碳

CO Separation by Imide/Imine Organic Cages.

作者信息

La Cognata Sonia, Mobili Riccardo, Milanese Chiara, Boiocchi Massimo, Gaboardi Mattia, Armentano Donatella, Jansen Johannes C, Monteleone Marcello, Antonangelo Ariana R, Carta Mariolino, Amendola Valeria

机构信息

Department of Chemistry, University of Pavia, Viale Tarquato Taramelli 12, Pavia, 27100, Italy.

Centro Grandi Strumenti, University of Pavia, Via Bassi 21, Pavia, 27100, Italy.

出版信息

Chemistry. 2022 Sep 1;28(49):e202201631. doi: 10.1002/chem.202201631. Epub 2022 Jul 25.

DOI:10.1002/chem.202201631
PMID:35762229
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9545214/
Abstract

Two novel imide/imine-based organic cages have been prepared and studied as materials for the selective separation of CO from N and CH under vacuum swing adsorption conditions. Gas adsorption on the new compounds showed selectivity for CO over N and CH . The cages were also tested as fillers in mixed-matrix membranes for gas separation. Dense and robust membranes were obtained by loading the cages in either Matrimid® or PEEK-WC polymers. Improved gas-transport properties and selectivity for CO were achieved compared to the neat polymer membranes.

摘要

已经制备并研究了两种新型的基于酰亚胺/亚胺的有机笼状物，作为在变压吸附条件下从氮气和甲烷中选择性分离一氧化碳的材料。在新化合物上的气体吸附显示出对一氧化碳的选择性高于氮气和甲烷。这些笼状物还作为气体分离混合基质膜中的填料进行了测试。通过将笼状物负载到Matrimid®或聚醚醚酮耐磨级（PEEK-WC）聚合物中，获得了致密且坚固的膜。与纯聚合物膜相比，实现了改善的气体传输性能和对一氧化碳的选择性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/be2c79990e0a/CHEM-28-0-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/2ddd515af9be/CHEM-28-0-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/978dd47dce61/CHEM-28-0-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/72f7e6f15e71/CHEM-28-0-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/e8abf232ffff/CHEM-28-0-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/a2fb2ddb25e3/CHEM-28-0-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/3d98c0ad37e1/CHEM-28-0-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/99caea516fc3/CHEM-28-0-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/4ae5f95d3e5e/CHEM-28-0-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/942575fac08d/CHEM-28-0-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/be2c79990e0a/CHEM-28-0-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/2ddd515af9be/CHEM-28-0-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/978dd47dce61/CHEM-28-0-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/72f7e6f15e71/CHEM-28-0-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/e8abf232ffff/CHEM-28-0-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/a2fb2ddb25e3/CHEM-28-0-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/3d98c0ad37e1/CHEM-28-0-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/99caea516fc3/CHEM-28-0-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/4ae5f95d3e5e/CHEM-28-0-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/942575fac08d/CHEM-28-0-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6dc9/9545214/be2c79990e0a/CHEM-28-0-g005.jpg

相似文献

1
CO Separation by Imide/Imine Organic Cages.通过酰亚胺/亚胺有机笼分离一氧化碳
Chemistry. 2022 Sep 1;28(49):e202201631. doi: 10.1002/chem.202201631. Epub 2022 Jul 25.
2
PEEK-WC-Based Mixed Matrix Membranes Containing Polyimine Cages for Gas Separation.基于聚酰亚胺笼的 PEEK-WC 混合基质膜用于气体分离。
Molecules. 2021 Sep 13;26(18):5557. doi: 10.3390/molecules26185557.
3
CO Separation by Imide/Imine Organic Cages.通过酰亚胺/亚胺有机笼进行一氧化碳分离
Chemistry. 2022 Sep 1;28(49):e202202357. doi: 10.1002/chem.202202357. Epub 2022 Aug 22.
4
Thin Film Composite Membranes Based on the Polymer of Intrinsic Microporosity PIM-EA(Me)-TB Blended with Matrimid5218.基于固有微孔聚合物PIM-EA(Me)-TB与Matrimid5218共混的复合薄膜
Membranes (Basel). 2022 Sep 13;12(9):881. doi: 10.3390/membranes12090881.
5
Mixed Matrix Membranes Using Porous Organic Polymers (POPs)-Influence of Textural Properties on CO/CH Separation.使用多孔有机聚合物（POPs）的混合基质膜——结构性质对CO/CH分离的影响
Polymers (Basel). 2023 Oct 18;15(20):4135. doi: 10.3390/polym15204135.
6
Molecular Characterization of Membrane Gas Separation under Very High Temperatures and Pressure: Single- and Mixed-Gas CO/CH and CO/N Permselectivities in Hybrid Networks.超高温高压下膜气体分离的分子表征：混合网络中单一气体和混合气体的CO/CH及CO/N渗透选择性
Membranes (Basel). 2022 May 17;12(5):526. doi: 10.3390/membranes12050526.
7
Development of highly permselective Mixed Matrix Membranes comprising of polyimide and Ln-MOF for CO capture.开发高选择性混合基质膜，包含聚酰亚胺和 Ln-MOF 用于 CO2 捕获。
Chemosphere. 2022 Nov;307(Pt 3):136051. doi: 10.1016/j.chemosphere.2022.136051. Epub 2022 Aug 14.
8
Biphenyl-Based Covalent Triazine Framework/Matrimid Mixed-Matrix Membranes for CO/CH Separation.用于CO/CH分离的联苯基金属有机骨架/Matrimid混合基质膜
Membranes (Basel). 2021 Oct 19;11(10):795. doi: 10.3390/membranes11100795.
9
Membranes with Molecular Gatekeepers for Efficient CO Capture and H Purification.具有分子守门人的膜用于高效二氧化碳捕获和氢气提纯
ACS Appl Mater Interfaces. 2024 Apr 11. doi: 10.1021/acsami.4c03088.
10
Mixed Matrix Membranes Loaded with a Porous Organic Polymer Having Bipyridine Moieties.负载含联吡啶基团多孔有机聚合物的混合基质膜。
Membranes (Basel). 2022 May 25;12(6):547. doi: 10.3390/membranes12060547.

引用本文的文献

1
Mixed Matrix Membranes Using Porous Organic Polymers (POPs)-Influence of Textural Properties on CO/CH Separation.使用多孔有机聚合物（POPs）的混合基质膜——结构性质对CO/CH分离的影响
Polymers (Basel). 2023 Oct 18;15(20):4135. doi: 10.3390/polym15204135.
2
The Difference in Performance and Compatibility between Crystalline and Amorphous Fillers in Mixed Matrix Membranes for Gas Separation (MMMs).用于气体分离的混合基质膜（MMMs）中结晶填料与非晶填料在性能和相容性方面的差异
Polymers (Basel). 2023 Jul 5;15(13):2951. doi: 10.3390/polym15132951.
3
Porous Metal-Organic Cages Based on Rigid Bicyclo[2.2.2]oct-7-ene Type Ligands: Synthesis, Structure, and Gas Uptake Properties.

本文引用的文献

1
Adjustable Functionalization of Hyper-Cross-Linked Polymers of Intrinsic Microporosity for Enhanced CO Adsorption and Selectivity over N and CH.用于增强对CO吸附及对N₂和CH₄选择性的本征微孔性超交联聚合物的可调功能化
ACS Appl Mater Interfaces. 2022 May 11;14(18):20997-21006. doi: 10.1021/acsami.2c02604. Epub 2022 Apr 26.
2
Chiroptical sensing of perrhenate in aqueous media by a chiral organic cage.手性有机笼在手性硒酸根在水相介质中的圆二色传感。
Chem Commun (Camb). 2022 Mar 22;58(24):3897-3900. doi: 10.1039/d2cc00612j.
3
A smart and responsive crystalline porous organic cage membrane with switchable pore apertures for graded molecular sieving.
基于刚性双环[2.2.2]辛-7-烯型配体的多孔金属-有机笼：合成、结构和气体吸附性能。
Chemistry. 2023 Jun 7;29(32):e202300732. doi: 10.1002/chem.202300732. Epub 2023 Apr 25.
一种智能响应的结晶多孔有机笼膜，具有可切换的孔径，用于分级分子筛。
Nat Mater. 2022 Apr;21(4):463-470. doi: 10.1038/s41563-021-01168-z. Epub 2022 Jan 10.
4
PEEK-WC-Based Mixed Matrix Membranes Containing Polyimine Cages for Gas Separation.基于聚酰亚胺笼的 PEEK-WC 混合基质膜用于气体分离。
Molecules. 2021 Sep 13;26(18):5557. doi: 10.3390/molecules26185557.
5
Life Cycle Assessment of Direct Air Carbon Capture and Storage with Low-Carbon Energy Sources.低碳能源直接空气碳捕集与封存的生命周期评估
Environ Sci Technol. 2021 Aug 17;55(16):11397-11411. doi: 10.1021/acs.est.1c03263. Epub 2021 Aug 5.
6
Porous shape-persistent rylene imine cages with tunable optoelectronic properties and delayed fluorescence.具有可调光电特性和延迟荧光的多孔形状持久苝酰亚胺笼状物。
Chem Sci. 2021 Mar 9;12(14):5275-5285. doi: 10.1039/d1sc00347j.
7
Solvatomorphism Influence of Porous Organic Cage on CH/CO Separation.多孔有机笼对CH/CO分离的溶剂同构影响。
ACS Appl Mater Interfaces. 2021 May 26;13(20):24042-24050. doi: 10.1021/acsami.1c04573. Epub 2021 May 12.
8
Isoreticular Crystallization of Highly Porous Cubic Covalent Organic Cage Compounds*.高孔隙率立方共价有机笼状化合物的等规结晶*
Angew Chem Int Ed Engl. 2021 Aug 2;60(32):17455-17463. doi: 10.1002/anie.202102982. Epub 2021 May 26.
9
Syntheses and evaluation of new hydrophilic azacryptands used as masking agents of technetium in solvent extraction processes.新的亲水性氮杂冠醚的合成与评价及其在溶剂萃取过程中作为锝掩蔽剂的应用。
Dalton Trans. 2021 Feb 9;50(5):1620-1630. doi: 10.1039/d0dt04210b.
10
Intrinsically Porous Molecular Materials (IPMs) for Natural Gas and Benzene Derivatives Separations.用于天然气和苯衍生物分离的本征微孔分子材料（IPMs）
Acc Chem Res. 2021 Jan 5;54(1):155-168. doi: 10.1021/acs.accounts.0c00582. Epub 2020 Dec 17.