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溶胶-凝胶转变编程壳聚糖水凝胶的自主推进。

Sol-gel transition programmed self-propulsion of chitosan hydrogel.

机构信息

Department of Physical Chemistry and Materials Science, University of Szeged, Rerrich Béla tér 1, Szeged H-6720, Hungary.

Department of Applied and Environmental Chemistry, University of Szeged, Rerrich Béla tér 1, Szeged H-6720, Hungary.

出版信息

Chaos. 2022 Jun;32(6):063120. doi: 10.1063/5.0097035.

DOI:10.1063/5.0097035
PMID:35778152
Abstract

Active soft materials exhibit various dynamics ranging from boat pulsation to thin membrane deformation. In the present work, in situ prepared ethanol-containing chitosan gels propel in continuous and intermittent motion. The active life of the organic material loaded to the constant fuel level follows a linear scaling, and its maximal velocity and projection area decrease steeply with chitosan concentration. A thin propelling platelet forms at low polymer content, leading to the suppression of intermittent motion. Moreover, the fast accelerating thin gels can split into a crescent and circular-like shape or fission into multiple asymmetric fragments.

摘要

活性软物质表现出各种动力学行为,从船波运动到薄膜变形。在本工作中,原位制备的含乙醇壳聚糖凝胶呈现连续和间歇运动。在恒定燃料水平下,负载的有机材料的活性寿命呈线性比例增加,其最大速度和投影面积随壳聚糖浓度的增加而急剧下降。在低聚合物含量下形成薄的推进薄片,导致间歇运动受到抑制。此外,快速加速的薄凝胶可以分裂成新月形和圆形,或者分裂成多个不对称的碎片。

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