Modeling and assessment of CO geological storage in the Eastern Deccan Basalt of India.

In this study, the CO carbonatization potential of the Deccan basalt formation in Eastern India is evaluated by establishing a hydro-chemical field-scale model based on the geological, hydrological, and geochemical parameter of the basalt in the Mandla lobe. The reliable initial mineral thermodynamic parameters are obtained by validating the laboratory scale experiment of CO-water-basalt reaction with a numerical method. Over 50% of injected carbon mineralized within 140 days for the Deccan basalt in the Mandla lobe, and the majority of CO is sequestered as ankerite, siderite, and calcite, which occupy a percent of 65%, 28%, and 7%, respectively. Clay minerals, including smectite and chlorite, are important secondary minerals contributing to the process of CO storage in the basaltic reservoir. Clay precipitation can promote the dissolution of silica- and aluminum-rich plagioclase and release Ca to enhance the carbonatization of CO to Ca carbonates but competes for Fe and Mg from siderite and magnesite. Clay precipitation also impacts the CO carbonatization efficiency by changing the basalt conductivity. CO carbonatization efficiency was found to increase with the reduction of injection rate. However, slow flow rate can increase the pore clogging risk and induce large pressure build-up. This is the first field-scale assessment of CO mineralization potential of the Deccan basalt, which is one of the largest terrestrial flood basalt formations in the world. The results can provide valuable information and scientific support for India and global carbon mitigation.